{"title":"基于热膨胀石墨的胶体石墨悬浮液","authors":"V. N. Gorshenev","doi":"10.1134/S1990793124700027","DOIUrl":null,"url":null,"abstract":"<p>Currently, modified oxidized (intercalated) graphites (OGs) and thermally expanded graphites (TEGs) obtained from them are used to solve many applied problems. This is due to the fact that while retaining all the properties of layered graphite compounds, split graphite particles have important new properties, such as ease of molding, low bulk density, and active interaction with the polymer matrix. However, the question of the mechanisms of expansion of OG and the properties of TEG particles split into layers has not been sufficiently studied. The establishment of experimental patterns of expansion processes of graphite oxidized by acids contributes to the understanding of the set of stages of complex processes occurring during the expansion of graphite particles in a gas atmosphere and in polymer matrices. The aim of this study is to synthesize a colloidal-graphite (CG) suspension based on TEG particles and determine the properties of suspensions and expansion processes of OG during thermal and microwave heating. As a result of modifying TEG with a low bulk density in the activating media, CG suspensions are synthesized without a vibration grinding stage. The splitting of graphite materials after chemical modification by thermal and microwave-stimulated heating leads to the formation of graphene-like structures. The development of techniques for modifying electrically conductive porous samples of materials used as electrodes makes it possible to introduce nanographite particles under the influence of an electric field.</p>","PeriodicalId":768,"journal":{"name":"Russian Journal of Physical Chemistry B","volume":"18 3","pages":"788 - 793"},"PeriodicalIF":1.4000,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Colloidal-Graphite Suspension Based on Thermally Expanded Graphite\",\"authors\":\"V. N. Gorshenev\",\"doi\":\"10.1134/S1990793124700027\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Currently, modified oxidized (intercalated) graphites (OGs) and thermally expanded graphites (TEGs) obtained from them are used to solve many applied problems. This is due to the fact that while retaining all the properties of layered graphite compounds, split graphite particles have important new properties, such as ease of molding, low bulk density, and active interaction with the polymer matrix. However, the question of the mechanisms of expansion of OG and the properties of TEG particles split into layers has not been sufficiently studied. The establishment of experimental patterns of expansion processes of graphite oxidized by acids contributes to the understanding of the set of stages of complex processes occurring during the expansion of graphite particles in a gas atmosphere and in polymer matrices. The aim of this study is to synthesize a colloidal-graphite (CG) suspension based on TEG particles and determine the properties of suspensions and expansion processes of OG during thermal and microwave heating. As a result of modifying TEG with a low bulk density in the activating media, CG suspensions are synthesized without a vibration grinding stage. The splitting of graphite materials after chemical modification by thermal and microwave-stimulated heating leads to the formation of graphene-like structures. The development of techniques for modifying electrically conductive porous samples of materials used as electrodes makes it possible to introduce nanographite particles under the influence of an electric field.</p>\",\"PeriodicalId\":768,\"journal\":{\"name\":\"Russian Journal of Physical Chemistry B\",\"volume\":\"18 3\",\"pages\":\"788 - 793\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-07-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Physical Chemistry B\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1990793124700027\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry B","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1990793124700027","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
引用次数: 0
摘要
摘要目前,改性氧化(插层)石墨(OGs)和由其制成的热膨胀石墨(TEGs)被用于解决许多应用问题。这是因为在保留层状石墨化合物所有特性的同时,裂解石墨颗粒具有重要的新特性,如易于成型、体积密度低以及与聚合物基体的相互作用活跃等。然而,关于 OG 的膨胀机制和分层 TEG 颗粒的特性问题还没有得到充分研究。建立酸氧化石墨膨胀过程的实验模式有助于了解石墨颗粒在气体环境和聚合物基质中膨胀时发生的一系列复杂过程。本研究的目的是以 TEG 颗粒为基础合成胶体石墨(CG)悬浮液,并确定悬浮液的性质以及热和微波加热过程中 OG 的膨胀过程。由于活化介质中的 TEG 体积密度较低,因此合成 CG 悬浮液无需振动研磨阶段。通过热和微波刺激加热对石墨材料进行化学改性后,石墨材料的分裂导致了类石墨烯结构的形成。对用作电极的材料的导电多孔样品进行改性的技术开发,使得在电场影响下引入纳米石墨颗粒成为可能。
Colloidal-Graphite Suspension Based on Thermally Expanded Graphite
Currently, modified oxidized (intercalated) graphites (OGs) and thermally expanded graphites (TEGs) obtained from them are used to solve many applied problems. This is due to the fact that while retaining all the properties of layered graphite compounds, split graphite particles have important new properties, such as ease of molding, low bulk density, and active interaction with the polymer matrix. However, the question of the mechanisms of expansion of OG and the properties of TEG particles split into layers has not been sufficiently studied. The establishment of experimental patterns of expansion processes of graphite oxidized by acids contributes to the understanding of the set of stages of complex processes occurring during the expansion of graphite particles in a gas atmosphere and in polymer matrices. The aim of this study is to synthesize a colloidal-graphite (CG) suspension based on TEG particles and determine the properties of suspensions and expansion processes of OG during thermal and microwave heating. As a result of modifying TEG with a low bulk density in the activating media, CG suspensions are synthesized without a vibration grinding stage. The splitting of graphite materials after chemical modification by thermal and microwave-stimulated heating leads to the formation of graphene-like structures. The development of techniques for modifying electrically conductive porous samples of materials used as electrodes makes it possible to introduce nanographite particles under the influence of an electric field.
期刊介绍:
Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.