微通道陶瓷甲醇转化器的设计与性能实验研究

IF 2.4 4区 化学 Q3 CHEMISTRY, PHYSICAL Ionics Pub Date : 2024-07-23 DOI:10.1007/s11581-024-05726-8
Haoming Sun, Dong Tang, Ruixiao Tian, Jinyan Tang
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引用次数: 0

摘要

氢气具有高能量密度和零碳排放的特点,是一种前景广阔的替代燃料。然而,目前氢气的储存和运输存在很大的安全风险。通过甲醇重整的现场制氢技术从根本上解决了氢气储存和运输的难题。本研究介绍了使用堇青石蜂窝陶瓷制造的微通道甲醇转化器的设计,并通过多参数实验对其运行性能进行了评估。结果表明,在反应温度为 553 K、水甲醇比为 1.25 和进料量为 0.4 ml/min 的条件下,可获得最佳重整性能。在这些条件下,甲醇转化率达到 84.99%,氢气产量为 361.69 ml/min,一氧化碳浓度为 0.6232%,在长期运行过程中表现出良好的稳定性。这项研究为甲醇转化炉的工业化和氢能利用提供了宝贵的启示。
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Design and performance experimental study of microchannel ceramic methanol reformer

Hydrogen possesses high energy density and emits zero carbon, making it a promising alternative fuel. However, the current storage and transportation of hydrogen pose significant safety risks. The on-site hydrogen production technology through methanol reforming offers a fundamental solution to the challenges of hydrogen storage and transportation. This study presents the design of a microchannel methanol reformer fabricated using cordierite honeycomb ceramics and evaluates its operational performance through multi-parameter experiments. The results show that optimal reforming performance is achieved at a reaction temperature of 553 K, a water-to-methanol ratio of 1.25, and a feed volume of 0.4 ml/min. Under these conditions, methanol conversion reaches 84.99%, hydrogen production amounts to 361.69 ml/min, and the carbon monoxide concentration is 0.6232%, demonstrating good stability during prolonged operation. This study provides valuable insights for the industrialization of methanol reformers and the utilization of hydrogen energy.

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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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