结合永磁搅拌和添加 La-Ce 实现 A356 铝合金凝固的新策略

Shuaijie Yuan, Jianfei Peng, Wanlin Wang, Peiyuan Gan, Junyu Ji, Jie Zeng
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摘要

A356 铝合金因其优异的机械性能和良好的耐腐蚀性而备受关注。在实际应用中,需要对共晶硅相进行精炼,以提高其机械性能。本研究提出了一种新策略,即在 A356 铝合金凝固过程中同时使用稀土 (RE) La 和 Ce 元素协同永磁搅拌 (PMS)。实验研究表明,共晶 Si 相从粗针状和片状形态转变为小颗粒形态,其平均尺寸从 12.94 μm 减小到 8.86 μm。我们注意到,La 和 Ce 的添加会在硅相中诱发孪晶和堆叠断层结构,阻止其进一步生长。同时,PMS 能显著细化 α-Al 相的晶粒尺寸,并在 Si 相前端生成更多小尺寸的 La-Ce 沉淀。当 PMS 和稀土同时应用时,PMS 产生的电磁力以及稀土元素 La 和 Ce 引发的孪晶和堆叠断层结构共同作用于 A356 合金,使 Si 相和α-Al 相都得到细化。精炼后的合金具有出色的机械性能和耐磨性。
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A New Strategy for a Combination of Permanent Magnet Stirring and La–Ce Addition Toward the Solidification of A356 Aluminum Alloy

A356 aluminum alloy has attracted enormous attention because of its excellent mechanical properties and good corrosion resistance. Refining the eutectic Si phase is required to improve the mechanical properties for practical applications. In this work, a new strategy is proposed by synergizing the permanent magnet stirring (PMS) with rare earth (RE) La and Ce elements simultaneously during the solidification of A356 aluminum alloy. Experimental studies reveal that the eutectic Si phase transforms from coarse needle-like and flake-like shapes to small granular morphology, and its average size reduces from 12.94 to 8.86 μm. It is noted that the additions of La and Ce can induce twins and stacking fault structures in the Si phase preventing its further growth. Meanwhile, the PMS can significantly refine the grain size of α-Al phase and generate more small size La–Ce precipitates at the front of Si phase. When PMS and rare earth are applied together, the electromagnetic force generated by PMS and the twins and stacking fault structures induced by rare earth elements La and Ce, collectively act on the A356 alloy to refine both the Si phase and α-Al phases. The refined alloy exhibits an outstanding combination of mechanical properties and wear resistance.

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