{"title":"使用锥形量热计测量可燃固体的火势增长潜力","authors":"Richard E Lyon","doi":"10.1177/07349041241263507","DOIUrl":null,"url":null,"abstract":"The fire growth rate of interior linings, furnishings, and construction materials is measured in full-scale fire tests such as the ASTM E84 Steiner Tunnel, the ISO 9705 room fire, and a passenger aircraft fuselage as the flame-spread rate, time-to-flashover, or time to incapacitation, respectively. The results are used to indicate the level of passive fire protection afforded by the combustible material or product in the test without providing any insight into the burning process. These large-scale tests require many square meters of product, are very expensive to conduct, and can exhibit poor repeatability–making them unsuitable for product development, quality control, product surveillance, or regulatory compliance. For this reason, smaller (0.01 m2) samples are tested in bench-scale fire calorimeters under controlled conditions, and these one-dimensional burning histories are correlated with the results of the two- and three-dimensional burning histories in full-scale fire tests by a variety of empirical and semi-empirical fire propagation indices, as well as analytic and computer models specific to the full-scale fire test. The approach described here defines the potential of a material to grow a fire in terms of cone calorimeter data obtained under standard conditions. The fire growth potential, λ (m2/J), is the coupled process of surface flame spread and in-depth burning that is defined as the product of ignitability (1/ E ign) and combustibility (Δ Q/Δ E) obtained from a combustion energy diagram measured in a cone calorimeter at an external radiant energy flux [Formula: see text] (W/m2) above the critical flux for burning, [Formula: see text]. However, the potential for fire growth, λ≡ (1/ Ei gn)(Δ Q/Δ E) is only realized as a hazard when the heat of combustion of the product per unit surface area, Hc (J/m2), is sufficient to grow the fire. The dimensionless fire hazard of a combustible product of thickness b is therefore, Π = λ Hc, while the fire hazard of the component materials is an average over the product thickness, π = Π/ b. The measurement of λ, Π, and π from combustion energy diagrams of heat release Q (J/m2) versus incident energy E (J/m2) is described, as well as a physical basis for a fire growth potential that provides simple analytic forms for λ in terms of the parameters reported in cone calorimeter tests. Experimental data from the literature show that rapid fire growth in full-scale fire tests of combustible materials occurs above a value of Π determined by the severity of the fire test.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Measuring the fire growth potential of combustible solids using a cone calorimeter\",\"authors\":\"Richard E Lyon\",\"doi\":\"10.1177/07349041241263507\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The fire growth rate of interior linings, furnishings, and construction materials is measured in full-scale fire tests such as the ASTM E84 Steiner Tunnel, the ISO 9705 room fire, and a passenger aircraft fuselage as the flame-spread rate, time-to-flashover, or time to incapacitation, respectively. The results are used to indicate the level of passive fire protection afforded by the combustible material or product in the test without providing any insight into the burning process. These large-scale tests require many square meters of product, are very expensive to conduct, and can exhibit poor repeatability–making them unsuitable for product development, quality control, product surveillance, or regulatory compliance. For this reason, smaller (0.01 m2) samples are tested in bench-scale fire calorimeters under controlled conditions, and these one-dimensional burning histories are correlated with the results of the two- and three-dimensional burning histories in full-scale fire tests by a variety of empirical and semi-empirical fire propagation indices, as well as analytic and computer models specific to the full-scale fire test. The approach described here defines the potential of a material to grow a fire in terms of cone calorimeter data obtained under standard conditions. The fire growth potential, λ (m2/J), is the coupled process of surface flame spread and in-depth burning that is defined as the product of ignitability (1/ E ign) and combustibility (Δ Q/Δ E) obtained from a combustion energy diagram measured in a cone calorimeter at an external radiant energy flux [Formula: see text] (W/m2) above the critical flux for burning, [Formula: see text]. However, the potential for fire growth, λ≡ (1/ Ei gn)(Δ Q/Δ E) is only realized as a hazard when the heat of combustion of the product per unit surface area, Hc (J/m2), is sufficient to grow the fire. The dimensionless fire hazard of a combustible product of thickness b is therefore, Π = λ Hc, while the fire hazard of the component materials is an average over the product thickness, π = Π/ b. The measurement of λ, Π, and π from combustion energy diagrams of heat release Q (J/m2) versus incident energy E (J/m2) is described, as well as a physical basis for a fire growth potential that provides simple analytic forms for λ in terms of the parameters reported in cone calorimeter tests. Experimental data from the literature show that rapid fire growth in full-scale fire tests of combustible materials occurs above a value of Π determined by the severity of the fire test.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-07-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1177/07349041241263507\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1177/07349041241263507","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
内衬、家具和建筑材料的火灾增长率是在全面火灾测试中测量的,如 ASTM E84 斯坦纳隧道、ISO 9705 室内火灾和客机机身,分别测量为火焰蔓延率、燃烧时间或丧失能力时间。测试结果用于说明可燃材料或产品在测试中提供的被动防火水平,而不提供任何有关燃烧过程的信息。这些大型测试需要很多平方米的产品,成本非常高,而且重复性差,因此不适合用于产品开发、质量控制、产品监督或法规遵从。因此,较小(0.01 平方米)的样品要在受控条件下用台式火烧热量计进行测试,并通过各种经验和半经验火灾传播指数以及专门针对全尺寸火烧测试的分析和计算机模型,将这些一维燃烧历史与全尺寸火烧测试中的二维和三维燃烧历史结果联系起来。这里介绍的方法是根据在标准条件下获得的锥形量热计数据来定义材料的火势增长潜力。火势增长潜力 λ (m2/J) 是表面火焰蔓延和深度燃烧的耦合过程,定义为可燃性(1/ E ign)和可燃性(Δ Q/Δ E)的乘积,该乘积是在外部辐射能量通量[计算公式:见正文](W/m2)高于燃烧临界通量[计算公式:见正文]的情况下,从锥形量热计测量的燃烧能量图中获得的。然而,只有当单位表面积产品的燃烧热 Hc (J/m2) 足以使火势蔓延时,火势蔓延的可能性 λ≡ (1/ Ei gn)(Δ Q/Δ E) 才会成为一种危险。因此,厚度为 b 的可燃产品的无量纲火灾危险性为 Π = λ Hc,而组成材料的火灾危险性为产品厚度的平均值 π = Π/ b。本文介绍了通过燃烧能量图(热释放 Q (J/m2) 与入射能量 E (J/m2))测量 λ、Π 和 π 的方法,以及火灾增长势能的物理基础,该基础可根据锥形量热计测试报告的参数提供 λ 的简单解析形式。文献中的实验数据表明,在可燃材料的全尺寸火灾试验中,火灾的快速增长发生在火灾试验严重程度所决定的 Π 值之上。
Measuring the fire growth potential of combustible solids using a cone calorimeter
The fire growth rate of interior linings, furnishings, and construction materials is measured in full-scale fire tests such as the ASTM E84 Steiner Tunnel, the ISO 9705 room fire, and a passenger aircraft fuselage as the flame-spread rate, time-to-flashover, or time to incapacitation, respectively. The results are used to indicate the level of passive fire protection afforded by the combustible material or product in the test without providing any insight into the burning process. These large-scale tests require many square meters of product, are very expensive to conduct, and can exhibit poor repeatability–making them unsuitable for product development, quality control, product surveillance, or regulatory compliance. For this reason, smaller (0.01 m2) samples are tested in bench-scale fire calorimeters under controlled conditions, and these one-dimensional burning histories are correlated with the results of the two- and three-dimensional burning histories in full-scale fire tests by a variety of empirical and semi-empirical fire propagation indices, as well as analytic and computer models specific to the full-scale fire test. The approach described here defines the potential of a material to grow a fire in terms of cone calorimeter data obtained under standard conditions. The fire growth potential, λ (m2/J), is the coupled process of surface flame spread and in-depth burning that is defined as the product of ignitability (1/ E ign) and combustibility (Δ Q/Δ E) obtained from a combustion energy diagram measured in a cone calorimeter at an external radiant energy flux [Formula: see text] (W/m2) above the critical flux for burning, [Formula: see text]. However, the potential for fire growth, λ≡ (1/ Ei gn)(Δ Q/Δ E) is only realized as a hazard when the heat of combustion of the product per unit surface area, Hc (J/m2), is sufficient to grow the fire. The dimensionless fire hazard of a combustible product of thickness b is therefore, Π = λ Hc, while the fire hazard of the component materials is an average over the product thickness, π = Π/ b. The measurement of λ, Π, and π from combustion energy diagrams of heat release Q (J/m2) versus incident energy E (J/m2) is described, as well as a physical basis for a fire growth potential that provides simple analytic forms for λ in terms of the parameters reported in cone calorimeter tests. Experimental data from the literature show that rapid fire growth in full-scale fire tests of combustible materials occurs above a value of Π determined by the severity of the fire test.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.