沸石-TQD 存在下的商业工业废水滇尼蓝染料光降解研究

Waleed M. Saad, W. Mohamed, Farid Sh. Mohamed, Ashraf elbendary
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摘要

去除污染物至关重要,对清洁水的需求、工业废水的增加以及环境污染都证明了这一点。利用沸石去除水和工业废水中的杂质是一种非常有效的方法。TiO 2 是沸石的一种特殊光物理特性,其特点是微孔多、吸收能力强、热化学稳定性好。溶胶凝胶法用于合成沸石和 TiO 2 量子点(TQD),其直径在 307 纳米到 48 纳米之间。在这项工作中,沸石微粒与 TiO 2 纳米粒子一起处理。使用扫描电子显微镜、漫反射光谱仪、布鲁瑙尔-艾美特-泰勒和 X 射线衍射仪对沸石/TiO 2 复合材料进行了评估。结果表明,TiO 2 纳米颗粒的存在降低了比表面积。然而,它却增强了吸收紫外线的能力。增加 TiO 2 的含量会使吸收边缘移动。利用蓝黛安染料去除分析评估了化合物的光催化特性。沸石-TQD 的比表面积为 292.39 m 2 /g,带隙能为 3.57 eV,是最有效的材料。通过分析废化学氧,我们获得了光催化性能增强的证据。我们还根据埃及环境法规定的 COD 限制值,确认了实际工业废水的光降解率。我们使用 COD 测量方法对九种回收的沸石-TQD 样品进行了检测。
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Study of Photodegradation of Dianix Blue Dye for Commercial Industrial Wastewater in the Presence of Zeolite-TQD
Pollutant removal is critical, as evidenced by the need for clean water, the rise in industrial effluent, and environmental pollution. One very efficient way to get rid of impurities from water and industrial effluent is to use zeolite removal. TiO 2 is one of the special photophysical characteristics of zeolite, which is distinguished by its numerous microscopic pores, high absorption capacity, and thermochemical stability. Sol-gel was used to synthesise zeolite and TiO 2 quantum dots (TQD) with diameters ranging from 307 to 48 nanometers. In this work, zeolite microparticles were treated with TiO 2 nanoparticles. The zeolite/TiO 2 composites were assessed using SEM, diffuse reflectance spectroscopy, Brunauer-Emmett-Teller, and X-ray diffractometer investigations. The results showed that the presence of TiO 2 nanoparticles reduces the specific surface area. However, it results in the ability to absorb ultraviolet rays. Increasing the amount of TiO 2 will cause the absorption edge to move. The photocatalytic properties of the compounds were evaluated using Blue Dianix dye removal analysis. Zeolite-TQD, with a specific surface area of 292.39 m 2 /g and a band gap energy of 3.57 eV, is the most effective material. Evidence of enhanced photocatalytic performance was obtained through analysis of spent chemical oxygen. We also confirmed the photodegradation rate of real industrial effluents using COD limitations specified in the Egyptian Environmental Law. Nine recycled zeolite-TQD samples were examined using COD measurements.
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