可再生无患子衍生多孔纳米球用于高效储能设备

Vandana Molahalli, Gowri Soman, V. Bhat, Jyothi M S, Uraiwan Sirimahachai, Sanjeev P Maradur, Paola De Padova, N. Chattham, G. Hegde
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摘要

近年来,从麝香树中提取的生物质碳质材料因其在储能设备(尤其是超级电容器)中的应用而备受关注。在本研究中,我们以香蕉皮为生物质前体,在不同温度(600、800 和 1000 摄氏度)下采用热解方法合成了碳质材料。利用不同的表征技术,如傅立叶变换红外光谱(FTIR)、XRD、FE-SEM 和 TEM,对制备的碳质材料 BP600、BP800 和 BP1000 进行了表征研究。通过循环伏安法(CV)、电静态充放电法(GCD)和电化学阻抗光谱法(EIS)对合成材料进行了电化学研究。以 3M KOH 为电解质的三电极系统对该材料的超级电容器性能进行了研究。结果表明,BP600 具有更好的比电容、更高的能量密度和功率密度,以及 16,000 周期的最大循环稳定性。为了证明 BP600 材料的实际应用性,我们还进行了两个电极系统的研究,结果显示比电容值较好,功率和能量密度值也可观。这项研究为我们提供了一种绿色方法,通过将生物废料转化为清洁的可再生能源,制造出无毒、低成本、环保的潜在多孔碳质电极材料。
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Renewable Musa Sapientum derived porous nano spheres for efficient energy storage devices
Biomass-based carbonaceous materials derived from Musa Sapientum have gained much attention in recent years for their application in energy storage devices, especially supercapacitors. In the present work, we synthesized carbonaceous material from banana peel as the biomass precursor by using a pyrolysis method carried out at various temperatures (600, 800, and 1000oC). The characterization of the prepared carbonaceous materials BP600, BP800 and BP1000 was done by using different characterization techniques such as FTIR, XRD, FE-SEM, and TEM, studies. The electrochemical study of the synthesized material was carried out by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) electrochemical impedance spectroscopy (EIS). The supercapacitive performance of the material was studied using a 3-electrode system with 3M KOH as an electrolyte. As a result, the BP600 exhibited a better specific capacitance with higher energy and power densities along with a maximum cyclic stability of 16,000 cycles. To show the practical applicability of the material BP 600, two electrode system studies were carried out as well, which showed preferentially good values for specific capacitance with appreciable power and energy density values. The study provides us with a green approach for the fabrication of non-toxic, low-cost, and environmentally friendly potential porous carbonaceous electrode materials by converting bio-waste into a clean and renewable source of energy.
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