Ti0.2V1.8CTx/V2O5 纳米复合材料的气体传感特性

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Russian Journal of Inorganic Chemistry Pub Date : 2024-07-31 DOI:10.1134/s0036023624600850
E. P. Simonenko, A. S. Mokrushin, I. A. Nagornov, V. M. Sapronova, Yu. M. Gorban, Ph. Yu. Gorobtsov, T. L. Simonenko, N. P. Simonenko, N. T. Kuznetsov
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引用次数: 0

摘要

摘要 通过对多层 MXene(一种二维碳化钒钛)进行相对低温的部分氧化,开发了一种生产纳米复合材料的方法,该复合材料包含一个 Ti0.2V1.8CTx MXene 内核和掺钛氧化钒表层。研究表明,在温度为 250°C 的空气环境中氧化初始 Ti0.2V1.8CTx 时,风琴状聚集体的微观结构得以保留,但由于形成了 V2O5,其组成层的孔隙率略有增加,厚度也有所增加。拉曼光谱证实了氧化钒的形成,并检测到 MXene 结构得以保留,其平面间距从 10.3 Å(初始 Ti0.2V1.8CTx 粉末)减小到 7.3 Å。开尔文探针力显微镜确定,在 Ti0.2V1.8CTx/V2O5 纳米复合材料的形成过程中,功函数从 4.88 eV(Ti0.2V1.8CTx)降至 4.68 eV。我们全面分析了通过微平板印刷沉积的 Ti0.2V1.8CTx/V2O5 层对多种气态分析物(H2、CO、NH3、NO2、C6H6、C3H6O、CH4、C2H5OH 和 O2)的化学感应特性。在较高的检测温度(125-200°C)下,检测到对氧气(10% O2)和二氧化氮(100 ppm)的高灵敏度;在整个温度范围(25-200°C)内,对湿度(50% RH)有明显的反应。如果检测温度为室温,则可观察到对丙酮、乙醇和氨的良好灵敏度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Gas-Sensing Properties of the Ti0.2V1.8CTx/V2O5 Nanocomposite

Abstract

A method was developed for producing a nanocomposite containing a Ti0.2V1.8CTx MXene core and surface layers of titanium-doped vanadium oxide by relatively low temperature partial oxidation of multilayer MXene, a two-dimensional vanadium titanium carbide. It was shown that, during the oxidation of the initial Ti0.2V1.8CTx in an air atmosphere at a temperature of 250°C, the microstructure of accordion-like aggregates is preserved with a slight increase in the porosity of their constituent layers and an increase in their thickness due to the formation of V2O5. The MXene structure was detected to be preserved with a decrease in the interplanar distance from 10.3 Å (initial Ti0.2V1.8CTx powder) to 7.3 Å. Raman spectroscopy confirmed the formation of vanadium oxide. Kelvin probe force microscopy determined that, in the formation of Ti0.2V1.8CTx/V2O5 nanocomposite, the work function decreases from 4.88 eV (Ti0.2V1.8CTx) to 4.68 eV. A comprehensive analysis was made of the chemosensory properties of Ti0.2V1.8CTx/V2O5 layers deposited by microplotter printing to a number of gaseous analytes (H2, CO, NH3, NO2, C6H6, C3H6O, CH4, C2H5OH, and O2). At elevated detection temperatures (125–200°C), high sensitivity to oxygen (10% O2) and NO2 (100 ppm) was detected; throughout the entire temperature range (25–200°C), there were noticeable responses to humidity (50% RH). If the temperature detection was room temperature, good sensitivity to acetone, ethanol, and ammonia was observed.

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来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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