M. D. Lebedev, A. A. Goncharenko, I. A. Skvortsov, M. S. Kuzmikov, A. S. Vashurin
{"title":"作为类石墨氮化碳前驱体的 SiO2@Melamine-Cyanurate 新型杂化材料的合成","authors":"M. D. Lebedev, A. A. Goncharenko, I. A. Skvortsov, M. S. Kuzmikov, A. S. Vashurin","doi":"10.1134/s0036023624600217","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>This work describes the use of silica particles obtained by sol-gel method as a template for deposition of supramolecular complexes of melamine cyanurate. To obtain SiO<sub>2</sub>@melamine-cyanurate (SiO<sub>2</sub>@MCA) material, the method of covalent modification of silica surface by melamine molecules (SiO<sub>2</sub>-mel) was applied and the method of its further functionalization by hydrogen-bonded organic framework of melamine-cyanurate (HOF, MCA) was proposed. One of the promising directions of using SiO<sub>2</sub>@melamine-cyanurate is obtaining the SiO<sub>2</sub>@g-C<sub>3</sub>N<sub>4</sub> material based on it. Control of the amount of applied melamine-cyanurate allows one to potentially obtain g-C<sub>3</sub>N<sub>4</sub> layers of different thicknesses on the silica surface.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of New Hybrid Materials of SiO2@Melamine-Cyanurate as Precursors for Graphite-Like Carbon Nitride\",\"authors\":\"M. D. Lebedev, A. A. Goncharenko, I. A. Skvortsov, M. S. Kuzmikov, A. S. Vashurin\",\"doi\":\"10.1134/s0036023624600217\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>This work describes the use of silica particles obtained by sol-gel method as a template for deposition of supramolecular complexes of melamine cyanurate. To obtain SiO<sub>2</sub>@melamine-cyanurate (SiO<sub>2</sub>@MCA) material, the method of covalent modification of silica surface by melamine molecules (SiO<sub>2</sub>-mel) was applied and the method of its further functionalization by hydrogen-bonded organic framework of melamine-cyanurate (HOF, MCA) was proposed. One of the promising directions of using SiO<sub>2</sub>@melamine-cyanurate is obtaining the SiO<sub>2</sub>@g-C<sub>3</sub>N<sub>4</sub> material based on it. Control of the amount of applied melamine-cyanurate allows one to potentially obtain g-C<sub>3</sub>N<sub>4</sub> layers of different thicknesses on the silica surface.</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-07-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1134/s0036023624600217\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s0036023624600217","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis of New Hybrid Materials of SiO2@Melamine-Cyanurate as Precursors for Graphite-Like Carbon Nitride
Abstract
This work describes the use of silica particles obtained by sol-gel method as a template for deposition of supramolecular complexes of melamine cyanurate. To obtain SiO2@melamine-cyanurate (SiO2@MCA) material, the method of covalent modification of silica surface by melamine molecules (SiO2-mel) was applied and the method of its further functionalization by hydrogen-bonded organic framework of melamine-cyanurate (HOF, MCA) was proposed. One of the promising directions of using SiO2@melamine-cyanurate is obtaining the SiO2@g-C3N4 material based on it. Control of the amount of applied melamine-cyanurate allows one to potentially obtain g-C3N4 layers of different thicknesses on the silica surface.
期刊介绍:
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.