{"title":"含二膦配体的钌-茚配合物的合成、结构和反应活性","authors":"Masumi Itazaki, Natsumi Kitani, Yukako Dobashi, Kento Okabayashi, Hiroshi Nakazawa, Toshiyuki Moriuchi","doi":"10.1002/ejic.202400415","DOIUrl":null,"url":null,"abstract":"<p>Ruthenium-indane complex, <i>fac-</i>[Ru(NCMe)<sub>3</sub>(CO)<sub>2</sub>(InCl<sub>3</sub>)] <b>1Cl</b> reacted with 0.5 equiv. of dppe/dppp to afford dinuclear ruthenium-indane complexes linked by diphosphine ligand, [{Ru(NCMe)<sub>2</sub>(CO)<sub>2</sub>(InCl<sub>3</sub>)}<sub>2</sub>{μ<sub>2</sub>-Ph<sub>2</sub>P(CH<sub>2</sub>)<sub>n</sub>PPh<sub>2</sub>}] (n=2: <b>3</b>, 3: <b>4</b>). On the other hand, the reaction of <i>fac-</i>[Ru(NCMe)<sub>3</sub>(CO)<sub>2</sub>(InCl<sub>3</sub>)] <b>1Cl</b> with 1 equiv. of dppp afforded the corresponding chelate ruthenium(0) indane complex, [Ru(NCMe)(CO)<sub>2</sub>(InCl<sub>3</sub>)(dppp)] <b>5</b>. In the case of dppm, a chelate complex [Ru(NCMe)(CO)<sub>2</sub>(InCl<sub>3</sub>)(dppm)] <b>6</b> was formed <i>via</i> the dinuclear Ru complex [{Ru(NCMe)<sub>2</sub>(CO)<sub>2</sub>(InCl<sub>3</sub>)}<sub>2</sub>(μ<sub>2</sub>-dppm)]. Complexes <b>1Cl</b>, <b>5</b>, and <b>6</b> showed a catalytic activity for double-hydrosilylation of MeCN. Complexes <b>3</b>–<b>6</b> were fully characterized using NMR measurements, elemental analyses, and the structures of <b>1Cl</b>, <b>3</b>, <b>5</b>, and <b>6</b> were determined by X-ray crystallography.</p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"27 29","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Structure, and Reactivity of Ruthenium-Indane Complexes with Diphosphine Ligand\",\"authors\":\"Masumi Itazaki, Natsumi Kitani, Yukako Dobashi, Kento Okabayashi, Hiroshi Nakazawa, Toshiyuki Moriuchi\",\"doi\":\"10.1002/ejic.202400415\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Ruthenium-indane complex, <i>fac-</i>[Ru(NCMe)<sub>3</sub>(CO)<sub>2</sub>(InCl<sub>3</sub>)] <b>1Cl</b> reacted with 0.5 equiv. of dppe/dppp to afford dinuclear ruthenium-indane complexes linked by diphosphine ligand, [{Ru(NCMe)<sub>2</sub>(CO)<sub>2</sub>(InCl<sub>3</sub>)}<sub>2</sub>{μ<sub>2</sub>-Ph<sub>2</sub>P(CH<sub>2</sub>)<sub>n</sub>PPh<sub>2</sub>}] (n=2: <b>3</b>, 3: <b>4</b>). On the other hand, the reaction of <i>fac-</i>[Ru(NCMe)<sub>3</sub>(CO)<sub>2</sub>(InCl<sub>3</sub>)] <b>1Cl</b> with 1 equiv. of dppp afforded the corresponding chelate ruthenium(0) indane complex, [Ru(NCMe)(CO)<sub>2</sub>(InCl<sub>3</sub>)(dppp)] <b>5</b>. In the case of dppm, a chelate complex [Ru(NCMe)(CO)<sub>2</sub>(InCl<sub>3</sub>)(dppm)] <b>6</b> was formed <i>via</i> the dinuclear Ru complex [{Ru(NCMe)<sub>2</sub>(CO)<sub>2</sub>(InCl<sub>3</sub>)}<sub>2</sub>(μ<sub>2</sub>-dppm)]. Complexes <b>1Cl</b>, <b>5</b>, and <b>6</b> showed a catalytic activity for double-hydrosilylation of MeCN. Complexes <b>3</b>–<b>6</b> were fully characterized using NMR measurements, elemental analyses, and the structures of <b>1Cl</b>, <b>3</b>, <b>5</b>, and <b>6</b> were determined by X-ray crystallography.</p>\",\"PeriodicalId\":38,\"journal\":{\"name\":\"European Journal of Inorganic Chemistry\",\"volume\":\"27 29\",\"pages\":\"\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-07-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202400415\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Inorganic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202400415","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis, Structure, and Reactivity of Ruthenium-Indane Complexes with Diphosphine Ligand
Ruthenium-indane complex, fac-[Ru(NCMe)3(CO)2(InCl3)] 1Cl reacted with 0.5 equiv. of dppe/dppp to afford dinuclear ruthenium-indane complexes linked by diphosphine ligand, [{Ru(NCMe)2(CO)2(InCl3)}2{μ2-Ph2P(CH2)nPPh2}] (n=2: 3, 3: 4). On the other hand, the reaction of fac-[Ru(NCMe)3(CO)2(InCl3)] 1Cl with 1 equiv. of dppp afforded the corresponding chelate ruthenium(0) indane complex, [Ru(NCMe)(CO)2(InCl3)(dppp)] 5. In the case of dppm, a chelate complex [Ru(NCMe)(CO)2(InCl3)(dppm)] 6 was formed via the dinuclear Ru complex [{Ru(NCMe)2(CO)2(InCl3)}2(μ2-dppm)]. Complexes 1Cl, 5, and 6 showed a catalytic activity for double-hydrosilylation of MeCN. Complexes 3–6 were fully characterized using NMR measurements, elemental analyses, and the structures of 1Cl, 3, 5, and 6 were determined by X-ray crystallography.
期刊介绍：
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
