华北克拉通南缘江北沟金矿床的成因:流体包裹体、H-O-S 同位素和黄铁矿原位微量元素分析的启示

IF 3.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Acta Geologica Sinica ‐ English Edition Pub Date : 2024-07-31 DOI:10.1111/1755-6724.15195
Fengchun LI, Qingdong ZENG, Rixiang ZHU, Shaoxiong CHU, Wei XIE, Bing YU, Jinjian WU, Xinghui LI
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引用次数: 0

摘要

涧北沟金矿床是位于华北克拉通南缘秦岭成矿带中的一个典型矿床。热液过程可分为三个阶段,包括石英±黄铁矿阶段、石英-多金属硫化物阶段和石英-碳酸盐±黄铁矿阶段。从早期到晚期,原生流体包裹体的均质化温度分别为 281-362°C、227-331°C 和 149-261°C。这些流体的相应盐度估计分别为 3.9-9.9%、0.4-9.4% 和 0.7-7.2%。结合激光拉曼光谱数据,成矿流体属于中低温、低盐度的 H2O-CO2-NaCl ± CH4 体系。石英脉的δ18Ofluid和δD值分别为-1.0‰至6.0‰和-105‰至-84‰,这表明成矿流体为混合来源,主要来自岩浆,也有陨石水的贡献。根据矿物副成因排序,黄铁矿被鉴定为三代,包括Py1、Py2和Py3。黄铁矿的δ34S硫同位素组成来自3.7‰和8.4‰之间的三个阶段,表明硫主要来源于岩浆。黄铁矿中 Te、Bi、Sb 和 Cu 的含量都很高,并且与金的浓度有很强的相关性。原生金和碲化金-银-铋矿物是同时形成的,而砷的浓度较低,且与金的含量脱钩。因此,Te、Bi、Sb 等低熔点亲铝元素对缺砷成矿流体中金的成矿具有重要作用。结合地质环境、黄铁矿演化和成矿流体地球化学,我们认为江北沟矿床可归类为岩浆-热液型金矿床。华北克拉通南缘的金矿化与早白垩世岩浆活动有关,是在延伸环境中形成的。
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Genesis of the Jianbeigou Gold Deposit on the Southern Margin of the North China Craton: Insights from Fluid Inclusions, H-O-S Isotopes, and Pyrite in situ Trace Element Analyses

The Jianbeigou gold deposit is a typical lode gold deposit in the Qinling metallogenic belt, located on the southern margin of the North China Craton. Three stages of the hydrothermal process can be distinguished, including the quartz ± pyrite, quartz-polymetallic sulfide, and quartz-carbonate ± pyrite stages. From the early to late stages, the homogenization temperatures of primary fluid inclusions are 281–362°C, 227–331°C, and 149–261°C, respectively. The corresponding salinities estimated for these fluids are 3.9–9.9 wt%, 0.4–9.4 wt%, and 0.7–7.2 wt% NaCl equiv. Combined with laser Raman spectroscopy data, the ore-forming fluid belongs to a H2O-CO2-NaCl ± CH4 system with medium–low temperature and salinity. The δ18Ofluid and δD values for the quartz veins are –1.0‰ to 6.0‰ and –105‰ to –84‰, respectively, which indicates that the ore-forming fluid is of mixed source, mainly derived from magma, with a contribution from meteoric water. Pyrite has been identified into three generations based on mineral paragenetic sequencing, including Py1, Py2, and Py3. The pyrites have δ34S sulfur isotopic compositions from three stages between 3.7‰ and 8.4‰, indicating that sulfur mainly originated from magma. Te, Bi, Sb, and Cu contents in pyrite were all high and showed a strong correlation with Au concentrations. Native gold and the Au-Ag-Bi telluride minerals were formed concurrently, and the As concentration was low and decoupled from the Au content. Therefore, Te, Bi, Sb and other low-melting point chalcophile elements play an important role for gold mineralization in arsenic-deficient ore-forming fluid. Combined with the geological setting, evolution of pyrite, and ore-fluids geochemistry, we propose that the Jianbeigou deposit can be classified as a magmatic–hydrothermal lode gold deposit. Gold mineralization on the southern margin of the North China Craton is related to Early Cretaceous magmatism and formed in an extensional setting.

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来源期刊
Acta Geologica Sinica ‐ English Edition
Acta Geologica Sinica ‐ English Edition 地学-地球科学综合
CiteScore
3.00
自引率
12.10%
发文量
3039
审稿时长
6 months
期刊介绍: Acta Geologica Sinica mainly reports the latest and most important achievements in the theoretical and basic research in geological sciences, together with new technologies, in China. Papers published involve various aspects of research concerning geosciences and related disciplines, such as stratigraphy, palaeontology, origin and history of the Earth, structural geology, tectonics, mineralogy, petrology, geochemistry, geophysics, geology of mineral deposits, hydrogeology, engineering geology, environmental geology, regional geology and new theories and technologies of geological exploration.
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