手性诱导自旋选择性的最小模型:自旋轨道耦合、隧道和退相干

IF 2.2 3区 物理与天体物理 Q2 MECHANICS Journal of Statistical Mechanics: Theory and Experiment Pub Date : 2024-08-01 DOI:10.1088/1742-5468/ad613b
Miguel Mena, Solmar Varela, Bertrand Berche and Ernesto Medina
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引用次数: 0

摘要

在此,我们回顾了手性诱导自旋选择性(CISS)作为手性分子中发生的独立效应的通用模型。我们将气相中的前向散射结果、手性自组装单层中的光电子结果以及两个末端传输装置中的最新结果结合在一起。我们讨论了迄今为止所有实验中必然存在的要素,我们将其确定为(i) 手性,无论是点手性、螺旋手性还是构型手性;(ii) 自旋轨道耦合,作为原子自旋主动耦合;(iii) 退相干,作为时间反转对称性破坏机制,避免了线性机制中的互易关系;最后 (iv) 隧道效应,解释了自旋极化效应的大小。这一建议并不排除其他机制,这些机制可以产生与分子与接触或基质的相互作用有关的类似自旋效应。最后,我们讨论了最近在对映体选择性、相干电子转移和自旋效应等领域的研究结果,这些结果表明 CISS 是一种分子现象。
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Minimal model for chirally induced spin selectivity: spin-orbit coupling, tunneling and decoherence
Here we review a universal model for chirally induced spin-selectivity (CISS) as a standalone effect occurring in chiral molecules. We tie together the results of forward scattering in the gas phase to the results for photoelectrons in chiral self-assembled monolayers, and the more contemporary results in two terminal transport setups. We discuss the ingredients that are necessarily present in all experiments to date, which we identify as: (i) chirality, be it point, helical or configurational, (ii) the spin–orbit coupling as the spin active coupling of atomic origin, (iii) decoherence as a time-reversal symmetry breaking mechanism that avoids reciprocity relations in the linear regime and finally (iv) tunneling that accounts for the magnitude of the spin polarization effect. This proposal does not discard other mechanisms that can yield comparable spin effects related to interactions of the molecule to contacts or substrates that have been proposed but are less universal or apply to specific situations. Finally, we discuss recent results suggesting CISS as a molecular phenomenon in the realms of enantiomer selectivity, coherent electron transfer, and spin effects in chiroptical activity.
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来源期刊
CiteScore
4.50
自引率
12.50%
发文量
210
审稿时长
1.0 months
期刊介绍: JSTAT is targeted to a broad community interested in different aspects of statistical physics, which are roughly defined by the fields represented in the conferences called ''Statistical Physics''. Submissions from experimentalists working on all the topics which have some ''connection to statistical physics are also strongly encouraged. The journal covers different topics which correspond to the following keyword sections. 1. Quantum statistical physics, condensed matter, integrable systems Scientific Directors: Eduardo Fradkin and Giuseppe Mussardo 2. Classical statistical mechanics, equilibrium and non-equilibrium Scientific Directors: David Mukamel, Matteo Marsili and Giuseppe Mussardo 3. Disordered systems, classical and quantum Scientific Directors: Eduardo Fradkin and Riccardo Zecchina 4. Interdisciplinary statistical mechanics Scientific Directors: Matteo Marsili and Riccardo Zecchina 5. Biological modelling and information Scientific Directors: Matteo Marsili, William Bialek and Riccardo Zecchina
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