热轧处理对 Zr-Sn-Co 三元合金微观结构、机械性能和腐蚀性能的影响

Chao-qun Xia, Hong-pu Zhou, Tian-shuo Song, Shu-guang Liu, Tai Yang, Qiang Li
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摘要

本实验研究了铸态 Zr-Sn-Co 三元合金的微观结构、机械性能和耐腐蚀性。研究了铸态 Zr-1.5Sn-xCo(x = 0、2.5、5、7.5 和 10 at.%)三元合金的性能,并确定了综合性能最佳的合金成分。随后,对所选合金进行了热轧处理。使用光学显微镜、X 射线衍射仪和扫描电子显微镜分析了合金在轧制状态下的微观结构。室温压缩试验和显微硬度试验分析了合金的机械性能,电化学试验研究了合金的腐蚀性能。结果表明,随着 Co 含量的增加,铸态 Zr-1.5Sn-Co 三元合金的强度显著提高。Co 元素的加入使铸造 Zr-1.5Sn-Co 合金的耐腐蚀性明显提高。热轧处理对提高 Zr-1.5Sn-2.5Co 合金的耐腐蚀性影响很小。但是,轧制处理后 Zr-1.5Sn-2.5Co 合金的机械性能明显提高。该合金在轧制温度为 600 ℃ 时强度和硬度最高,在轧制温度为 800 ℃ 时塑性最好。
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Effect of hot rolling treatment on microstructure, mechanical, and corrosion properties of Zr–Sn–Co ternary alloys

The microstructure, mechanical properties, and corrosion resistance of as-cast Zr–Sn–Co ternary alloys have been investigated in this experiment. The properties of as-cast Zr–1.5Sn–xCo (x = 0, 2.5, 5, 7.5, and 10 at.%) ternary alloys were investigated, and the alloy composition exhibiting the best comprehensive performance was identified. Subsequently, the chosen alloys were subjected to hot rolling treatment. The microstructure of the alloys in the rolled state was analyzed using the optical microscope, X-ray diffractometer, and scanning electron microscope. The mechanical properties of the alloys were analyzed using room temperature compression tests and microhardness tests, while the corrosion properties of the alloy were investigated through electrochemical testing. The results show that the strength of as-cast Zr–1.5Sn–Co ternary alloy increases significantly with the increase in Co content. The incorporation of Co element makes the corrosion resistance of as-cast Zr–1.5Sn–Co alloy increase significantly. The hot rolling treatment has minimal effect on enhancing the corrosion resistance of Zr–1.5Sn–2.5Co alloy. However, the mechanical properties of Zr–1.5Sn–2.5Co alloy after rolling treatment are significantly enhanced. The alloy exhibits the highest strength and hardness at a rolling temperature of 600 °C and exhibits the best plasticity at a rolling temperature of 800 °C.

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来源期刊
自引率
16.00%
发文量
161
审稿时长
2.8 months
期刊介绍: Publishes critically reviewed original research of archival significance Covers hydrometallurgy, pyrometallurgy, electrometallurgy, transport phenomena, process control, physical chemistry, solidification, mechanical working, solid state reactions, materials processing, and more Includes welding & joining, surface treatment, mathematical modeling, corrosion, wear and abrasion Journal of Iron and Steel Research International publishes original papers and occasional invited reviews on aspects of research and technology in the process metallurgy and metallic materials. Coverage emphasizes the relationships among the processing, structure and properties of metals, including advanced steel materials, superalloy, intermetallics, metallic functional materials, powder metallurgy, structural titanium alloy, composite steel materials, high entropy alloy, amorphous alloys, metallic nanomaterials, etc..
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