Jiyoung Park , Tugba G. Kucukkal , Jung-Min Oh , Steven J. Stuart , Stephen E. Creager , Gustavo Muñoz , Dennis W. Smith Jr.
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We report a selective [2 + 2] cyclo-copolymerization of aryl trifluorovinyl ethers (TFVEs) toward segmented copolymers. Experimental and computational studies confirm that copolymerization of relatively electron-rich and electron-poor TFVE monomers results in segmented copolymers in a single polymerization. The effect of microstructures on post-sulfonation in the polymer backbones was also investigated.
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Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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