具有矩形不对称波形的 DIT 的质量选择性不稳定性和共振喷射模式。

IF 1.1 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL European Journal of Mass Spectrometry Pub Date : 2024-06-01 Epub Date: 2024-08-07 DOI:10.1177/14690667241270234
A I Ivanov, A A Sysoev, N V Konenkov
{"title":"具有矩形不对称波形的 DIT 的质量选择性不稳定性和共振喷射模式。","authors":"A I Ivanov, A A Sysoev, N V Konenkov","doi":"10.1177/14690667241270234","DOIUrl":null,"url":null,"abstract":"<p><p>We consider the operation of a digital linear ion trap with resonance radial ejection and mass selective instability modes. Periodic wave shape has a positive part with amplitude <math><msup><mi>V</mi><mo>+</mo></msup><mo>=</mo><msub><mi>V</mi><mn>0</mn></msub></math> and duration <math><mn>0.8</mn><mi>T</mi></math> and negative part with amplitude <math><msup><mi>V</mi><mo>-</mo></msup><mo>=</mo><mo>-</mo><mn>4</mn><msub><mi>V</mi><mn>0</mn></msub></math> and duration <math><mn>0.2</mn><mi>T</mi></math>, where <i>T</i> is the period. The mapping of the stability diagram, calculations of the well's depth and ion oscillations spectra are presented. The process of resonant excitation of ion oscillations by a dipole sinusoidal signal is studied, as well as ion ejection at the stability boundary. The trajectory method is used for this purpose. It is shown that the mass selectivity of dipole excitation is twice as large for rectangular wave shape compared to sinusoidal wave shape. Increasing the diameter of the round rods of the linear trap gives an increase in the resolving power. The possibility of DIT operation in mass-selective instability mode at the boundary point <math><msub><mi>q</mi><mi>b</mi></msub><mo>=</mo><mn>0.39</mn></math> is discussed.</p>","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":" ","pages":"143-149"},"PeriodicalIF":1.1000,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mass-selective instability and resonance ejection modes for DIT with rectangular asymmetric wave shape.\",\"authors\":\"A I Ivanov, A A Sysoev, N V Konenkov\",\"doi\":\"10.1177/14690667241270234\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>We consider the operation of a digital linear ion trap with resonance radial ejection and mass selective instability modes. Periodic wave shape has a positive part with amplitude <math><msup><mi>V</mi><mo>+</mo></msup><mo>=</mo><msub><mi>V</mi><mn>0</mn></msub></math> and duration <math><mn>0.8</mn><mi>T</mi></math> and negative part with amplitude <math><msup><mi>V</mi><mo>-</mo></msup><mo>=</mo><mo>-</mo><mn>4</mn><msub><mi>V</mi><mn>0</mn></msub></math> and duration <math><mn>0.2</mn><mi>T</mi></math>, where <i>T</i> is the period. The mapping of the stability diagram, calculations of the well's depth and ion oscillations spectra are presented. The process of resonant excitation of ion oscillations by a dipole sinusoidal signal is studied, as well as ion ejection at the stability boundary. The trajectory method is used for this purpose. It is shown that the mass selectivity of dipole excitation is twice as large for rectangular wave shape compared to sinusoidal wave shape. Increasing the diameter of the round rods of the linear trap gives an increase in the resolving power. The possibility of DIT operation in mass-selective instability mode at the boundary point <math><msub><mi>q</mi><mi>b</mi></msub><mo>=</mo><mn>0.39</mn></math> is discussed.</p>\",\"PeriodicalId\":12007,\"journal\":{\"name\":\"European Journal of Mass Spectrometry\",\"volume\":\" \",\"pages\":\"143-149\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Mass Spectrometry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1177/14690667241270234\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/8/7 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Mass Spectrometry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/14690667241270234","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/8/7 0:00:00","PubModel":"Epub","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
引用次数: 0

摘要

我们考虑了具有共振径向喷射和质量选择不稳定模式的数字线性离子阱的运行。周期波形的正波段振幅为 V+=V0,持续时间为 0.8T;负波段振幅为 V-=-4V0,持续时间为 0.2T,其中 T 为周期。报告介绍了稳定图的绘制、井深计算和离子振荡谱。研究了偶极正弦信号对离子振荡的共振激励过程,以及稳定边界的离子喷射。为此采用了轨迹法。结果表明,与正弦波形相比,矩形波形的偶极子激发的质量选择性是正弦波形的两倍。增加线性阱圆棒的直径可提高分辨能力。讨论了 DIT 在边界点 qb=0.39 的质量选择不稳定模式下运行的可能性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Mass-selective instability and resonance ejection modes for DIT with rectangular asymmetric wave shape.

We consider the operation of a digital linear ion trap with resonance radial ejection and mass selective instability modes. Periodic wave shape has a positive part with amplitude V+=V0 and duration 0.8T and negative part with amplitude V-=-4V0 and duration 0.2T, where T is the period. The mapping of the stability diagram, calculations of the well's depth and ion oscillations spectra are presented. The process of resonant excitation of ion oscillations by a dipole sinusoidal signal is studied, as well as ion ejection at the stability boundary. The trajectory method is used for this purpose. It is shown that the mass selectivity of dipole excitation is twice as large for rectangular wave shape compared to sinusoidal wave shape. Increasing the diameter of the round rods of the linear trap gives an increase in the resolving power. The possibility of DIT operation in mass-selective instability mode at the boundary point qb=0.39 is discussed.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
2.40
自引率
7.70%
发文量
16
审稿时长
>12 weeks
期刊介绍: JMS - European Journal of Mass Spectrometry, is a peer-reviewed journal, devoted to the publication of innovative research in mass spectrometry. Articles in the journal come from proteomics, metabolomics, petroleomics and other areas developing under the umbrella of the “omic revolution”.
期刊最新文献
Clustering of biphenyl oxamide ions by chiral recognition. Analysis of dimer and trimer complexes of the non-amyloidogenic rat islet amyloid polypeptide 21-37 by electrospray ionization-tandem mass spectrometry. Exploring the versatility of mass spectrometry: Applications across diverse scientific disciplines. Bioanalytical method development and validation of docetaxel and carvacrol in mice plasma using LC-QqQ-MS/MS. Ion crystal size and structure in Paul traps.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1