{"title":"[1-(蒽-9-基甲基)-1,4,7,10-四氮杂环十二烯]氯化锌硝酸盐。","authors":"Yoshimi Ichimaru , Kirara Sugiura , Koichi Kato , Yuki Kondo , Masaaki Kurihara , Wanchun Jin , Masanori Imai , Hiromasa Kurosaki","doi":"10.1107/S2414314624006655","DOIUrl":null,"url":null,"abstract":"<div><p>The Zn<sup>II</sup> atom in the complex cation of the title salt has a square-pyramidal coordination environment defined by four nitrogen atoms from cyclen (1,4,7,10-tetraazacyclododecane) in the basal plane and one chlorido ligand in the apical position.</p></div><div><p>In the title salt, [ZnCl(C<sub>23</sub>H<sub>30</sub>N<sub>4</sub>)]NO<sub>3</sub>, the central Zn<sup>II</sup> atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitrogen atoms from cyclen (1,4,7,10-tetraazacyclododecane) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through intermolecular T-shaped π interactions. Additionally, the nitrate anion participates in intermolecular N—H⋯O hydrogen bonds with cyclen.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (294KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></p></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 7","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11299653/pdf/","citationCount":"0","resultStr":"{\"title\":\"[1-(Anthracen-9-ylmethyl)-1,4,7,10-tetraazacyclododecane]chloridozinc(II) nitrate\",\"authors\":\"Yoshimi Ichimaru , Kirara Sugiura , Koichi Kato , Yuki Kondo , Masaaki Kurihara , Wanchun Jin , Masanori Imai , Hiromasa Kurosaki\",\"doi\":\"10.1107/S2414314624006655\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Zn<sup>II</sup> atom in the complex cation of the title salt has a square-pyramidal coordination environment defined by four nitrogen atoms from cyclen (1,4,7,10-tetraazacyclododecane) in the basal plane and one chlorido ligand in the apical position.</p></div><div><p>In the title salt, [ZnCl(C<sub>23</sub>H<sub>30</sub>N<sub>4</sub>)]NO<sub>3</sub>, the central Zn<sup>II</sup> atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitrogen atoms from cyclen (1,4,7,10-tetraazacyclododecane) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through intermolecular T-shaped π interactions. Additionally, the nitrate anion participates in intermolecular N—H⋯O hydrogen bonds with cyclen.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (294KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></p></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 7\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11299653/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000658\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000658","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
在标题盐[ZnCl(C23H30N4)]NO3 中，络合物阳离子的中心 ZnII 原子与环烯（1,4,7,10-四氮杂环十二烯）的四个硝基原子在基面上以方阵排列方式配位，一个氯配体在顶端位置配位。环烯上的蒽基通过分子间的 T 型 π 相互作用形成晶体结构。此外，硝酸阴离子还与环烯形成分子间 N-H⋯O 氢键。
The ZnII atom in the complex cation of the title salt has a square-pyramidal coordination environment defined by four nitrogen atoms from cyclen (1,4,7,10-tetraazacyclododecane) in the basal plane and one chlorido ligand in the apical position.
In the title salt, [ZnCl(C23H30N4)]NO3, the central ZnII atom of the complex cation is coordinated in a square-pyramidal arrangement by four nitrogen atoms from cyclen (1,4,7,10-tetraazacyclododecane) in the basal plane and one chlorido ligand in the apical position. The anthracene group attached to cyclen contributes to the crystal packing through intermolecular T-shaped π interactions. Additionally, the nitrate anion participates in intermolecular N—H⋯O hydrogen bonds with cyclen.
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