Bertin Anzaldo , René Gutiérrez Pérez , Guadalupe Hernández Téllez , Ángel Mendoza , Gloria E. Moreno Morales
{"title":"双{(S)-(-)-N-[(2-联苯基)甲基-亚烯]-1-(4-甲氧基-苯基)乙胺-κN}二氯钯(II)。","authors":"Bertin Anzaldo , René Gutiérrez Pérez , Guadalupe Hernández Téllez , Ángel Mendoza , Gloria E. Moreno Morales","doi":"10.1107/S2414314624005558","DOIUrl":null,"url":null,"abstract":"<div><p>The Pd atom is coordinated by two nitrogen atoms from two <em>trans</em>-aligned imine ligands and two chlorine atoms in an essentially square-planar environment.</p></div><div><p>The Pd<sup>II</sup> complex bis{(<em>S</em>)-(−)-<em>N</em>-[(biphenyl-2-yl)methylidene]1-(4-methoxyphenyl)ethanamine-κ<em>N</em>}dichloridopalladium(II), [PdCl<sub>2</sub>(C<sub>22</sub>H<sub>21</sub>NO)<sub>2</sub>], crystallizes in the monoclinic Sohncke space group <em>P</em>2<sub>1</sub> with a single molecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N—Pd—Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd—Cl and Pd—N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features intermolecular N—H⋯Cl and intramolecular C—H⋯Pd interactions, which lead to the formation of a supramolecular framework structure.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (305KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></p></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 7","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11299657/pdf/","citationCount":"0","resultStr":"{\"title\":\"Bis{(S)-(−)-N-[(2-biphenyl)methylidene]-1-(4-methoxyphenyl)ethylamine-κN}dichloridopalladium(II)\",\"authors\":\"Bertin Anzaldo , René Gutiérrez Pérez , Guadalupe Hernández Téllez , Ángel Mendoza , Gloria E. Moreno Morales\",\"doi\":\"10.1107/S2414314624005558\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Pd atom is coordinated by two nitrogen atoms from two <em>trans</em>-aligned imine ligands and two chlorine atoms in an essentially square-planar environment.</p></div><div><p>The Pd<sup>II</sup> complex bis{(<em>S</em>)-(−)-<em>N</em>-[(biphenyl-2-yl)methylidene]1-(4-methoxyphenyl)ethanamine-κ<em>N</em>}dichloridopalladium(II), [PdCl<sub>2</sub>(C<sub>22</sub>H<sub>21</sub>NO)<sub>2</sub>], crystallizes in the monoclinic Sohncke space group <em>P</em>2<sub>1</sub> with a single molecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N—Pd—Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd—Cl and Pd—N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features intermolecular N—H⋯Cl and intramolecular C—H⋯Pd interactions, which lead to the formation of a supramolecular framework structure.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (305KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></p></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 7\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11299657/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000701\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000701","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The Pd atom is coordinated by two nitrogen atoms from two trans-aligned imine ligands and two chlorine atoms in an essentially square-planar environment.
The PdII complex bis{(S)-(−)-N-[(biphenyl-2-yl)methylidene]1-(4-methoxyphenyl)ethanamine-κN}dichloridopalladium(II), [PdCl2(C22H21NO)2], crystallizes in the monoclinic Sohncke space group P21 with a single molecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N—Pd—Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd—Cl and Pd—N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features intermolecular N—H⋯Cl and intramolecular C—H⋯Pd interactions, which lead to the formation of a supramolecular framework structure.
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