通过激光熔覆在 Q235 基材上制作自润滑抗磨损 316L 不锈钢/h-BN 复合涂层并确定其特性

Yun Chen, Yuliang Xu, Tao Li, Juan Du, Lingyu Guo, Kaixiong Hu
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摘要

本文介绍了利用 316L 不锈钢粉末和纳米级六方氮化硼(h-BN)陶瓷颗粒,通过同轴粉末进给激光熔覆技术,在 Q235 基材上制作自润滑抗磨损 316L 不锈钢复合涂层并对其进行表征。研究了工艺参数对熔覆质量和几何形状的影响,以及 h-BN 含量(2 wt% 和 5 wt%)对涂层微观结构和机械性能的影响。确定了 316L/5wt%BN 涂层的最佳工艺参数:粉末进给速度为 3-4 rpm,激光功率为 2200-2400 W,扫描速度为 4-5 mm/s,重叠率为 40%。微观结构分析表明,涂层表面光滑,无裂纹或气孔。X 射线衍射显示出金属间化合物,如 CrB、CrN、FeN、BN 和 γ-(Fe、Ni)。h-BN 纳米粒子的加入增强了晶粒细化,显著提高了显微硬度。含有 5 wt% h-BN 的涂层的平均显微硬度达到了 438.8 HV10,是基体和 316L 不锈钢的 2.5 倍。此外,h-BN 还降低了摩擦系数,从而大幅减少了磨损。316L/5 wt% h-BN 样品的磨损量仅为 4.2 毫克,是基体磨损量的 45.16%。这些发现凸显了 h-BN 纳米粒子对 316L 不锈钢涂层的有利影响,可提高耐磨性、硬度和整体性能。
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Fabrication and characterization of self-lubricating anti-wear 316L stainless steel/h-BN composite coatings on Q235 substrate via laser cladding
This paper presents the fabrication and characterization of self-lubricating, anti-wear 316L stainless steel composite coatings on a Q235 substrate using 316L stainless steel powders and nanoscale hexagonal boron nitride (h-BN) ceramic particles via coaxial powder feeding laser cladding. The influence of process parameters on cladding quality and geometry, and the impact of h-BN contents (2 wt% and 5 wt%) on the microstructure and mechanical properties of the coatings were studied. Optimal process parameters for 316L/5wt%BN coatings were identified: a powder feeding rate of 3–4 rpm, a laser power of 2200–2400 W, a scanning speed of 4–5 mm/s, and an overlapping rate of 40 %. Microstructural analysis showed a smooth surface without cracks or pores. X-ray diffraction revealed intermetallic compounds such as CrB, CrN, FeN, BN, and γ-(Fe, Ni). The inclusion of h-BN nanoparticles enhanced grain refinement, significantly increasing microhardness. Coatings with 5 wt% h-BN achieved an average microhardness of 438.8 HV10, 2.5 times higher than the substrate and the 316L stainless steel. Additionally, h-BN reduced friction coefficients, leading to substantial wear reduction. The 316L/5 wt% h-BN sample experienced only 4.2 mg of wear, 45.16 % of the substrate’s wear. These findings highlight the beneficial effects of h-BN nanoparticles on 316L stainless steel coatings, enhancing wear resistance, hardness, and overall performance.
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