在多孔单晶聚合物支撑的钯催化剂上进行烯烃的马尔科夫尼科夫选择性加氢氨基羰基化反应

IF 5.4 3区材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-08-27 DOI:10.1039/d4cy00742e

Jiajun Li , Kang Zhao , Xinjiang Cui , Lailai Wang , Feng Shi

{"title":"在多孔单晶聚合物支撑的钯催化剂上进行烯烃的马尔科夫尼科夫选择性加氢氨基羰基化反应","authors":"Jiajun Li , Kang Zhao , Xinjiang Cui , Lailai Wang , Feng Shi","doi":"10.1039/d4cy00742e","DOIUrl":null,"url":null,"abstract":"<div><p>Here we develop a porous monophoshine polymer supported Pd catalyst (Pd/POL-<em>m</em>-3vPPh<sub>3</sub>) for hydroaminocarbonylation of aromatic alkenes with amines, showing excellent catalytic activity (up to 97% yield) and Markovnikov selectivity (up to 99%) for producing branched amides. This catalyst exhibits broad substrate compatibility, and is reused for two times with no significant decline in the performance and three times with no significant Pd leaching, as well as applied for the synthesis of naproxen.</p></div>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":null,"pages":null},"PeriodicalIF":5.4000,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Markovnikov selective hydroaminocarbonylation of alkenes over a porous monophoshine polymer supported palladium catalyst†\",\"authors\":\"Jiajun Li , Kang Zhao , Xinjiang Cui , Lailai Wang , Feng Shi\",\"doi\":\"10.1039/d4cy00742e\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Here we develop a porous monophoshine polymer supported Pd catalyst (Pd/POL-<em>m</em>-3vPPh<sub>3</sub>) for hydroaminocarbonylation of aromatic alkenes with amines, showing excellent catalytic activity (up to 97% yield) and Markovnikov selectivity (up to 99%) for producing branched amides. This catalyst exhibits broad substrate compatibility, and is reused for two times with no significant decline in the performance and three times with no significant Pd leaching, as well as applied for the synthesis of naproxen.</p></div>\",\"PeriodicalId\":4,\"journal\":{\"name\":\"ACS Applied Energy Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.4000,\"publicationDate\":\"2024-08-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Energy Materials\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2044475324004301\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Energy Materials","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2044475324004301","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

摘要

在此，我们开发了一种多孔单晶聚合物支撑钯催化剂（Pd/POL-m-3vPPh3），用于芳香族烯烃与胺的加氢氨基羰基化反应，在生成支链酰胺方面表现出优异的催化活性（产率高达 97%）和马尔科夫尼科夫选择性（高达 99%）。该催化剂具有广泛的底物相容性，重复使用两次性能无明显下降，三次无明显钯浸出，并可用于合成萘普生。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

摘要图片

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Markovnikov selective hydroaminocarbonylation of alkenes over a porous monophoshine polymer supported palladium catalyst†

Here we develop a porous monophoshine polymer supported Pd catalyst (Pd/POL-m-3vPPh₃) for hydroaminocarbonylation of aromatic alkenes with amines, showing excellent catalytic activity (up to 97% yield) and Markovnikov selectivity (up to 99%) for producing branched amides. This catalyst exhibits broad substrate compatibility, and is reused for two times with no significant decline in the performance and three times with no significant Pd leaching, as well as applied for the synthesis of naproxen.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

ACS Applied Energy Materials Materials Science-Materials Chemistry

CiteScore

10.30

自引率

6.20%

发文量

1368

期刊介绍： ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.