{"title":"论逆乳液聚合中的成核和单体迁移机理","authors":"F. Joseph Schork","doi":"10.1002/mren.202400017","DOIUrl":null,"url":null,"abstract":"<p>A rationale for droplet nucleation during inverse emulsion polymerization (IEP) (reported by previous investigators) is proposed. Based on the idea that smaller monomer droplets are nucleated into polymer particles, while larger droplets serve as reservoirs for monomer (as in a micellar nucleation mechanism) the question of possible monomer-transport limitation during polymerization is explored.</p>","PeriodicalId":18052,"journal":{"name":"Macromolecular Reaction Engineering","volume":"18 6","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2024-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mren.202400017","citationCount":"0","resultStr":"{\"title\":\"On the Mechanism of Nucleation and Monomer Transport in Inverse Emulsion Polymerization\",\"authors\":\"F. Joseph Schork\",\"doi\":\"10.1002/mren.202400017\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A rationale for droplet nucleation during inverse emulsion polymerization (IEP) (reported by previous investigators) is proposed. Based on the idea that smaller monomer droplets are nucleated into polymer particles, while larger droplets serve as reservoirs for monomer (as in a micellar nucleation mechanism) the question of possible monomer-transport limitation during polymerization is explored.</p>\",\"PeriodicalId\":18052,\"journal\":{\"name\":\"Macromolecular Reaction Engineering\",\"volume\":\"18 6\",\"pages\":\"\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-08-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mren.202400017\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Reaction Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/mren.202400017\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Reaction Engineering","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/mren.202400017","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
On the Mechanism of Nucleation and Monomer Transport in Inverse Emulsion Polymerization
A rationale for droplet nucleation during inverse emulsion polymerization (IEP) (reported by previous investigators) is proposed. Based on the idea that smaller monomer droplets are nucleated into polymer particles, while larger droplets serve as reservoirs for monomer (as in a micellar nucleation mechanism) the question of possible monomer-transport limitation during polymerization is explored.
期刊介绍：
Macromolecular Reaction Engineering is the established high-quality journal dedicated exclusively to academic and industrial research in the field of polymer reaction engineering.
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