Manan S. Patel, Jaydeepkumar N. Parekh, Dipakkumar D. Chudasama, Harsh C. Patel, Manish Kumar Mishra, Jeebanjyoti Mohapatra and Kesur R. Ram*,
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引用次数: 0
摘要
在目前的技术水平下,我们报道了用生态健康的低值生物质(LVBM)巨鲁胺合成任务特异性CuI纳米粒子(NPs)的单锅绿色方法。利用各种分析工具对合成的巨鲁明封装 CuI NPs(Meg-Cu)材料进行了表征,发现 CuI NPs(大小为 100 nm)被巨鲁明分子与巨鲁明的 -NHMe 和 -OH 官能相互作用而封装。镁铜作为催化剂被用于创造 1,2,3-三唑支架,效果奇佳。所建立的方案允许通过双组分和三组分路线合成 1,2,3-三唑。此外,该方案还可通过原位生成芳香叠氮化物,有效地用于合成由苯胺引发的 1,2,3-三唑。催化剂可成功循环使用三次,且不会丧失催化活性。通过傅立叶变换红外光谱和热重分析研究了废催化剂的结构完整性。本方案具有反应时间短、底物范围广、反应条件对环境友好、产率高至优等特点。
Meglumine Encapsulated CuI: A Green Heterogeneous Catalyst Derived from Low Value Biomass Meglumine to Access 1,2,3-Triazole Scaffolds
In current state of the art, we report a solitary pot green tactic for the synthesis of task-specific CuI nanoparticles (NPs) encapsulated by eco-healthy low value biomass (LVBM) meglumine. The synthesized meglumine encapsulated CuI NPs (Meg-Cu) material was characterized by using various analytical tools, and it was found that CuI NPs (with <100 nm size) were encapsulated by meglumine molecules interacting with −NHMe and −OH functionalities of meglumine. Meg-Cu was utilized marvelously as a catalyst for the creation of 1,2,3-triazole scaffolds. The established protocol allowed the synthesis of 1,2,3-triazoles via both two- and three-component routes. Moreover, the protocol was efficiently used for the synthesis of 1,2,3-triazoles initiated from anilines via in-situ generation of aromatic azides. The catalyst was successfully recycled up to three times without a loss of catalytic activity. The structural integrity of the spent catalyst was investigated by FT-IR and TGA analysis. The present protocol embraces features like a short reaction time, wide substrate scope, environment-friendly reaction conditions, and good to excellent yields.