由 1,3,5-三氮杂-7-磷杂环[3.3.1.1]癸烷 (PTA) 及衍生物稳定的金属复合物促进的催化反应。最新成果概览

IF 2.7 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Inorganica Chimica Acta Pub Date : 2024-08-03 DOI:10.1016/j.ica.2024.122295

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引用次数: 0

摘要

在这篇综述文章中，我们简要回顾了近期（2018-2024 年）出现在科学文献中的文章，介绍了笼状水溶性单齿膦 1,3,5- 三氮杂-7-磷杂三环[3.3.1.1]癸烷（又称 1,3,5-三氮杂-7-磷杂金刚烷，PTA）、其一些衍生物和更高的同系物作为贵金属和非贵金属络合物的稳定配体，在水和双相介质中的均相催化过程中有多种应用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Catalytic reactions promoted by metal complexes stabilized by 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. A brief survey of recent results

In this review article, we present a brief survey of the recent contributions (2018–2024) appeared in the scientific literature, describing the use of the cage-like water-soluble monodentate phosphine 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (also known as 1,3,5-triaza-7-phosphadamantane, PTA), some of its derivatives and a higher homologue as stabilizing ligands for precious and non-precious metal complexes, with various applications in homogeneous catalytic processes in water and biphasic media.

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来源期刊

Inorganica Chimica Acta 化学-无机化学与核化学

CiteScore

6.00

自引率

3.60%

发文量

440

审稿时长

35 days

期刊介绍： Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews. Topics covered include: • chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies; • synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs); • reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models; • applications of inorganic compounds, metallodrugs and molecule-based materials. Papers composed primarily of structural reports will typically not be considered for publication.