增强氢化 $β_{12}$ 硼吩的超导性

Božidar N. Šoškić, Jonas Bekaert, Cem Sevik, Milorad V. Milošević
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引用次数: 0

摘要

硼吩因其非凡的物理性质而在元素二维材料中脱颖而出,包括结构多态性、强各向异性、金属性以及声子介导的超导潜力。然而,主要由于金属基底的不利影响及其易氧化性,迄今为止还无法通过实验证实硼吩中的超导性。在这项研究中,我们对实验合成的氢化$\beta_{12}$硼吩中的超导性进行了文本{ab initio}分析,这种硼吩已被证实不易被氧化。我们的研究结果表明,氢化可以显著提高 $\beta_{12}$ 硼吩的稳定性和超导特性。这些发现不仅促进了超导硼铼及其异质结构的进一步基础研究,而且将氢化硼铼定位为低维超导电子学的多功能平台。
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Enhanced superconductivity of hydrogenated $β_{12}$ borophene
Borophene stands out among elemental two-dimensional materials due to its extraordinary physical properties, including structural polymorphism, strong anisotropy, metallicity, and the potential for phonon-mediated superconductivity. However, confirming superconductivity in borophene experimentally has been evasive to date, mainly due to the detrimental effects of metallic substrates and its susceptibility to oxidation. In this study, we present an \textit{ab initio} analysis of superconductivity in the experimentally synthesized hydrogenated $\beta_{12}$ borophene, which has been proven to be less prone to oxidation. Our findings demonstrate that hydrogenation significantly enhances both the stability and superconducting properties of $\beta_{12}$ borophene. Furthermore, we reveal that tensile strain and hole doping, achievable through various experimental methods, significantly enhance the critical temperature, reaching up to 29 K. These findings not only promote further fundamental research on superconducting borophene and its heterostructures, but also position hydrogenated borophene as a versatile platform for low-dimensional superconducting electronics.
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