Single-Particle Model of Li-ion Battery – Model Calibration and Validation against Real Data in an Electric Vehicular Application⁎

This paper investigates the problem of calibration and validation of a battery electrochemical model as a mandatory step towards accurate estimation of battery important variables, like state of charge (SoC) and state of health (SoH). Here, the Single Particle Model (SPM) is considered, which mathematically describes the battery internal governing phenomena by means of parabolic partial differential equations (PDEs), but whose parameters are notoriously difficult to measure or estimate. After suitable approximation of this model through a linear finite-dimensional model, a systematic procedure of SPM calibration is here proposed and validated against real data issued from battery cycling in an electric vehicular application, i.e., under standard driving cycle scenarios. In a novel approach of SoC estimation, the suitably calibrated SPM, together with measures of voltage and current, allow to analytically connect the internal spatially distributed ions’ concentrations to the equilibrium concentration, which, at its turn, is an image of battery SoC. Results suggest that SPM can reliably predict the battery internal ions’ concentrations and be further used for SoC accurate estimation.