探索溶色性:4-硝基-2-氰基偶氮苯-甲基甲苯胺溶剂-绝对相互作用研究数据的综合分析。

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY BMC Chemistry Pub Date : 2024-08-19 DOI:10.1186/s13065-024-01249-5
Mahdi Shirali, Shohre Rouhani, Kamaladin Gharanjig, Fatemeh Mirhashemi
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引用次数: 0

摘要

本研究调查了一种新型 D1 分散染料的溶解变色行为,重点是 4-硝基-2-氰基偶氮苯-间甲苯胺类型。我们利用紫外可见光谱分析了染料在单一溶剂和二元混合物中的性能。我们的分析包括溶剂极性参数和染料结构参数的评估,重点是最长波长的分子内电荷转移吸收带。我们确定了电子转变能量图中与溶剂成分有关的非线性和线性模式。统计分析考虑了相关系数、均方根误差、平均绝对百分比误差和其他参数,提供了对数据准确性和精确性的见解。这项实验和统计研究探讨了一种新型偶氮染料在不同溶剂和溶质环境中的吸收光谱、波长特征、吸收能量和极性。这些发现有助于全面了解该染料的光物理和光化学特性,从而有可能将其应用于光学传感器和先进材料中。
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Exploring solvatochromism: a comprehensive analysis of research data of the solvent -solute interactions of 4-nitro-2-cyano-azo benzene-meta toluidine

This study investigates the solvatochromic behavior of a new D1 disperse dye, focusing on the 4-nitro-2-cyano-azo-Benzene-metaToluidine type. Using UV-visible spectroscopy, we analyze the dye’s performance in single solvents and binary mixtures. Our analysis includes the evaluation of solvent polarity parameters and dye structure parameters, with emphasis on the longest wavelength intramolecular charge transfer absorption band. We identify nonlinear and linear patterns in the electronic transition energies plots with respect to solvent composition. Statistical analysis considers correlation coefficients, root mean squared error, mean absolute percentage error, and other parameters, providing insights into data accuracy and precision. This experimental and statistical study explores the absorption spectrum, wavelength characteristics, absorption energy, and polarity of a novel azo dye across various solvent and solute environments. These findings contribute to a comprehensive understanding of the dye’s photophysical and photochemical properties, potentially enabling applications in optical sensors and advanced materials.

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来源期刊
BMC Chemistry
BMC Chemistry Chemistry-General Chemistry
CiteScore
5.30
自引率
2.20%
发文量
92
审稿时长
27 weeks
期刊介绍: BMC Chemistry, formerly known as Chemistry Central Journal, is now part of the BMC series journals family. Chemistry Central Journal has served the chemistry community as a trusted open access resource for more than 10 years – and we are delighted to announce the next step on its journey. In January 2019 the journal has been renamed BMC Chemistry and now strengthens the BMC series footprint in the physical sciences by publishing quality articles and by pushing the boundaries of open chemistry.
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