An organic visible-photocatalytic-adsorbence mechanism to high-efficient removal of heavy metal antimony ions

Purification of emerging heavy metal antimony contaminated water based on advanced ingenious strategies. An activated modified coconut shell charcoal (CSC) was synthesized and evaluated as a substrate-supported loaded organic photovoltaic material, PM6:PYIT:PM6-b-PYIT, to prepare a surprisingly highly efficient, stable, environmentally friendly, and recyclable organic photocatalyst (CSC–N–P.P.P), which showed excellent effects on the simultaneous removal of Sb(III) and Sb(V). The removal efficiency of CSC-N-P.P.P on Sb(Ⅲ) and Sb(V) reached an amazing 99.9% in quite a short duration of 15 min. At the same time, under ppb level and indoor visible light (∼1 W m⁻²), it can be treated to meet the drinking water standards set by the European Union and the U.S. National Environmental Protection Agency in 5 min, and even after 25 cycles of recycling, the efficiency is still maintained at about 80%, in addition to the removal of As (III), Cd (II), Cr (VI), and Pb (II) can also be realized. The catalyst not only solves the problems of low reuse rate, difficult structure adjustment and high energy consumption of traditional photocatalysts but also has strong applicability and practical significance. The pioneering approach provides a much-needed solution strategy for removing highly toxic heavy metal antimony pollution from the environment.