{"title":"利用机械合金工艺生产高熵 (FeNiMnCrV)3O4 氧化物及锂离子电池电化学性能分析","authors":"","doi":"10.1016/j.jssc.2024.124978","DOIUrl":null,"url":null,"abstract":"<div><p>In this study, a high entropy oxide material was fabricated from its alloy using mechanical alloying technique in the form of (FeNiMnCrV)<sub>3</sub>O<sub>4</sub> with a symmetry of Fd-3m, and their structural properties were investigated by XRD, SEM-EDS dot mapping, and XPS analyses. The EDS analysis results of oxide and alloy show that Fe, Ni, Mn, Cr, and V have similar ratios for both samples. The elemental ratios were also measured by ICP-MS and the results support the EDS and XPS data. The alloy and oxide powders were used for the production of the anode materials for the half-cell configuration of the battery. The CV analysis of both cells showed that they have similar characteristic redox reactions and the main difference between the two electrodes is the current density values in the peaks. The initial capacity value of the (FeNiMnCrV)<sub>3</sub>O<sub>4</sub> for 10 mA/g was found as 1070 mAh/g for the first cycle which is promising results as an anode material for Li-ion cells.</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":null,"pages":null},"PeriodicalIF":3.2000,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Production of high entropy (FeNiMnCrV)3O4 oxide by mechanical alloying process and electrochemical performance analysis for Li-ion cells\",\"authors\":\"\",\"doi\":\"10.1016/j.jssc.2024.124978\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this study, a high entropy oxide material was fabricated from its alloy using mechanical alloying technique in the form of (FeNiMnCrV)<sub>3</sub>O<sub>4</sub> with a symmetry of Fd-3m, and their structural properties were investigated by XRD, SEM-EDS dot mapping, and XPS analyses. The EDS analysis results of oxide and alloy show that Fe, Ni, Mn, Cr, and V have similar ratios for both samples. The elemental ratios were also measured by ICP-MS and the results support the EDS and XPS data. The alloy and oxide powders were used for the production of the anode materials for the half-cell configuration of the battery. The CV analysis of both cells showed that they have similar characteristic redox reactions and the main difference between the two electrodes is the current density values in the peaks. The initial capacity value of the (FeNiMnCrV)<sub>3</sub>O<sub>4</sub> for 10 mA/g was found as 1070 mAh/g for the first cycle which is promising results as an anode material for Li-ion cells.</p></div>\",\"PeriodicalId\":378,\"journal\":{\"name\":\"Journal of Solid State Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-08-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Solid State Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022459624004328\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Solid State Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022459624004328","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Production of high entropy (FeNiMnCrV)3O4 oxide by mechanical alloying process and electrochemical performance analysis for Li-ion cells
In this study, a high entropy oxide material was fabricated from its alloy using mechanical alloying technique in the form of (FeNiMnCrV)3O4 with a symmetry of Fd-3m, and their structural properties were investigated by XRD, SEM-EDS dot mapping, and XPS analyses. The EDS analysis results of oxide and alloy show that Fe, Ni, Mn, Cr, and V have similar ratios for both samples. The elemental ratios were also measured by ICP-MS and the results support the EDS and XPS data. The alloy and oxide powders were used for the production of the anode materials for the half-cell configuration of the battery. The CV analysis of both cells showed that they have similar characteristic redox reactions and the main difference between the two electrodes is the current density values in the peaks. The initial capacity value of the (FeNiMnCrV)3O4 for 10 mA/g was found as 1070 mAh/g for the first cycle which is promising results as an anode material for Li-ion cells.
期刊介绍:
Covering major developments in the field of solid state chemistry and related areas such as ceramics and amorphous materials, the Journal of Solid State Chemistry features studies of chemical, structural, thermodynamic, electronic, magnetic, and optical properties and processes in solids.