使用 D2O 作为氘源,铜催化芳基硼酸/硼酸盐的脱硼脱碘反应。

IF 2.9 3区 化学 Q1 CHEMISTRY, ORGANIC Organic & Biomolecular Chemistry Pub Date : 2024-08-28 DOI:10.1039/D4OB01251H
Mingqi Yang, Tao Chen, Ze-Feng Xu, Mingming Yu and Chuan-Ying Li
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引用次数: 0

摘要

利用具有成本效益的氘源 D2O,实现了芳基硼酸和硼酸盐的直接铜催化脱氘反应。该方案具有广泛的底物适用性、卓越的氘掺入效率以及对各种官能团的良好耐受性。因此,这种方法为进一步应用于有价值的氘分子合成提供了温和的选择。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Copper-catalyzed deborodeuteration of arylboronic acids/borates using D2O as the deuterium source†

A straightforward copper-catalyzed deborodeuteration of arylboronic acids and borates was achieved, employing the cost-effective deuterium source D2O. This protocol demonstrates wide substrate applicability, exceptional deuterium incorporation efficiency, and favorable tolerance for various functional groups. Therefore, this approach offers a mild option for further applications in valuable deuterium molecule synthesis.

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来源期刊
Organic & Biomolecular Chemistry
Organic & Biomolecular Chemistry 化学-有机化学
CiteScore
5.50
自引率
9.40%
发文量
1056
审稿时长
1.3 months
期刊介绍: The international home of synthetic, physical and biomolecular organic chemistry.
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