以光化学 C-H 溴化反应为介导的醛与醇的直接氧化酯化反应。

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-09-06 DOI:10.1039/d4ob01237b

Haru Ando, Sakura Kodaki, Hiroyoshi Takamura, Isao Kadota, Kenta Tanaka

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引用次数: 0

摘要

本报告中介绍的通过原位生成的酰基溴对醛和醇进行光化学直接酯化的方法，是对迄今已报道的方法的一种极具吸引力的补充，因为这些方法通常是通过两步、一锅程序进行的，以避免副反应，如卤素源对醇的氧化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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A direct oxidative esterification of aldehydes with alcohols mediated by photochemical C-H bromination.

The photochemical direct esterification of aldehydes with alcohols via in situ-generated acyl-bromides presented in this report is an attractive complementary addition to hitherto reported methods, as these are usually carried out in a two-step, one-pot procedure in order to avoid side reactions such as the oxidation of alcohols by halogen sources.

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来源期刊

ACS Applied Bio Materials Chemistry-Chemistry (all)

CiteScore

9.40

自引率

2.10%

发文量

464