Fumitoshi Yagishita, Shoma Mukai, Sota Abe, Shoko Ueta, Yasushi Yoshida, Yukihiro Arakawa, Keiji Minagawa and Yasushi Imada
{"title":"四芳基[3]积雪烯通过亲电碘代环化作用向苯并呋喃的机械化学转化†","authors":"Fumitoshi Yagishita, Shoma Mukai, Sota Abe, Shoko Ueta, Yasushi Yoshida, Yukihiro Arakawa, Keiji Minagawa and Yasushi Imada","doi":"10.1039/D4MR00022F","DOIUrl":null,"url":null,"abstract":"<p >We demonstrate solvent-free mechanochemical iodocyclization of tetraaryl[3]cumulenes using <em>N</em>-iodosuccinimides as the first example of the molecular transformation of cumulenes based on mechanochemistry. This mechanochemical reaction provides the corresponding benzofulvenes in good yields, overcoming the limitation of conventional methods using organic solvents.</p>","PeriodicalId":101140,"journal":{"name":"RSC Mechanochemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/mr/d4mr00022f?page=search","citationCount":"0","resultStr":"{\"title\":\"Mechanochemical transformation of tetraaryl[3]cumulenes to benzofulvenes via electrophilic iodocyclization†\",\"authors\":\"Fumitoshi Yagishita, Shoma Mukai, Sota Abe, Shoko Ueta, Yasushi Yoshida, Yukihiro Arakawa, Keiji Minagawa and Yasushi Imada\",\"doi\":\"10.1039/D4MR00022F\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >We demonstrate solvent-free mechanochemical iodocyclization of tetraaryl[3]cumulenes using <em>N</em>-iodosuccinimides as the first example of the molecular transformation of cumulenes based on mechanochemistry. This mechanochemical reaction provides the corresponding benzofulvenes in good yields, overcoming the limitation of conventional methods using organic solvents.</p>\",\"PeriodicalId\":101140,\"journal\":{\"name\":\"RSC Mechanochemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2024/mr/d4mr00022f?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"RSC Mechanochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/mr/d4mr00022f\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"RSC Mechanochemistry","FirstCategoryId":"1085","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/mr/d4mr00022f","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Mechanochemical transformation of tetraaryl[3]cumulenes to benzofulvenes via electrophilic iodocyclization†
We demonstrate solvent-free mechanochemical iodocyclization of tetraaryl[3]cumulenes using N-iodosuccinimides as the first example of the molecular transformation of cumulenes based on mechanochemistry. This mechanochemical reaction provides the corresponding benzofulvenes in good yields, overcoming the limitation of conventional methods using organic solvents.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
