{"title":"通过钯催化串联铃木偶联/赫克环化反应合成双环芳香烯和相关多环系统","authors":"","doi":"10.1016/j.tetlet.2024.155297","DOIUrl":null,"url":null,"abstract":"<div><p>A variety of bistricyclic aromatic enes (BAEs) and its derivatives have been prepared via the palladium-catalyzed Suzuki coupling/Heck cyclization tandem reaction in one pot. In the new proposal the expected products were obtained in exciting yields at nearly equimolar ratios of the substrates. It is very useful method for the synthesis of the fluorenylidene-based BAEs. Even the corresponding ladder-type conjugated polymer was also prepared by the tandem reaction.</p></div>","PeriodicalId":438,"journal":{"name":"Tetrahedron Letters","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of bistricyclic aromatic enes and related polycyclic systems via Pd-catalyzed tandem Suzuki coupling/Heck cyclization reaction\",\"authors\":\"\",\"doi\":\"10.1016/j.tetlet.2024.155297\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A variety of bistricyclic aromatic enes (BAEs) and its derivatives have been prepared via the palladium-catalyzed Suzuki coupling/Heck cyclization tandem reaction in one pot. In the new proposal the expected products were obtained in exciting yields at nearly equimolar ratios of the substrates. It is very useful method for the synthesis of the fluorenylidene-based BAEs. Even the corresponding ladder-type conjugated polymer was also prepared by the tandem reaction.</p></div>\",\"PeriodicalId\":438,\"journal\":{\"name\":\"Tetrahedron Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-09-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0040403924003927\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040403924003927","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Synthesis of bistricyclic aromatic enes and related polycyclic systems via Pd-catalyzed tandem Suzuki coupling/Heck cyclization reaction
A variety of bistricyclic aromatic enes (BAEs) and its derivatives have been prepared via the palladium-catalyzed Suzuki coupling/Heck cyclization tandem reaction in one pot. In the new proposal the expected products were obtained in exciting yields at nearly equimolar ratios of the substrates. It is very useful method for the synthesis of the fluorenylidene-based BAEs. Even the corresponding ladder-type conjugated polymer was also prepared by the tandem reaction.
期刊介绍:
Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.