以甲烷和氢气为燃料的扁平管状固体氧化物燃料电池的性能和应力分析

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-08-14 DOI:10.1007/s10338-024-00514-3
Chengrong Yu, Zhiyuan Guo, Zehua Pan, Yexin Zhou, Hongying Zhang, Bin Chen, Peng Tan, Wanbing Guan, Zheng Zhong
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引用次数: 0

摘要

固体氧化物燃料电池(SOFC)是一种前景广阔的发电技术,具有效率高、可使用多种燃料的特点。虽然 H2 的输送和储存仍是障碍,但天然气可通过现有管道基础设施随时获取,因此是 SOFC 的可行候选燃料。由于工作温度较高,天然气中的甲烷可以直接在 SOFC 的阳极中转化。然而,机械故障仍然是一个关键问题,阻碍了传统平面 SOFC 的普及。之前有人提出了一种具有对称双面阴极的新型扁管结构,以提高机械耐久性。在这项研究中,我们利用多物理场数值模型分析了采用对称双面阴极的甲烷燃料 SOFC 的性能。研究了 SOFC 中不同物理场的分布。其中特别关注了应力分析,这与 SOFC 的机械稳定性密切相关。此外,还比较了以 CH4 为燃料和以 H2 为燃料的 SOFC 的热应力分布。在以 CH4 为燃料的扁管 SOFC 中观察到较低的第一主应力,这表明机械故障的概率降低,并有可能延长使用寿命。
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Performance and Stress Analysis of Flat-Tubular Solid Oxide Fuel Cells Fueled with Methane and Hydrogen

Solid oxide fuel cell (SOFC) is a promising power generation technology with high efficiency and can operate with a wide range of fuels. Although H2 delivery and storage are still hurdles, natural gas is readily accessible through existing pipeline infrastructure and therefore stands as a viable fuel candidate for SOFC. Owing to the high operating temperature, the methane in natural gas can be directly reformed in the anode of an SOFC. However, mechanical failure remains a critical issue and hinders the prevalence of traditional planar SOFCs. A novel flat-tubular structure with symmetrical double-sided cathodes was previously proposed to improve mechanical durability. In this work, the performance of a methane-fueled SOFC with symmetrical double-sided cathodes is analyzed with a numerical multiphysics model. The distributions of different physical fields in the SOFC are investigated. Special attention is paid to stress analysis, which is closely related to the mechanical stability of an SOFC. Furthermore, the CH4-fueled and H2-fueled SOFCs are also compared in terms of the distribution of thermal stress. A lower first principal stress is observed for CH4-fueled flat-tubular SOFC, demonstrating a reduced probability of mechanical failures and potentially extended lifespan.

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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
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