一种新型复合催化剂 α-nBACoPc/SnO2 协同光催化降解染料

IF 0.8 4区 化学 Q4 SPECTROSCOPY Journal of Applied Spectroscopy Pub Date : 2024-09-12 DOI:10.1007/s10812-024-01804-x
Yanbing Yin, Bei Jiang, Guopeng Xu, Yang Liu, Zhou Wang, Yongming Feng, Xinyu Sun
{"title":"一种新型复合催化剂 α-nBACoPc/SnO2 协同光催化降解染料","authors":"Yanbing Yin,&nbsp;Bei Jiang,&nbsp;Guopeng Xu,&nbsp;Yang Liu,&nbsp;Zhou Wang,&nbsp;Yongming Feng,&nbsp;Xinyu Sun","doi":"10.1007/s10812-024-01804-x","DOIUrl":null,"url":null,"abstract":"<p>The α-nBACoPc/SnO<sub>2</sub> composites were prepared using the in situ synthesis method and characterized by Fourier transform infrared (FT-IR), X-ray powder diff raction (XRD), X-ray photoelectron spectroscopy (XPS), and confirmed by the loading of amino cobalt phthalocyanine on SnO<sub>2</sub>. Conduct photocatalytic degradation experiments used rhodamine B as a simulated pollutant. The composite exhibited a photo-catalytic degradation rate of 83.3%, which was higher than that of α-nBACoPc and SnO<sub>2</sub> alone. The Co–O bond in the composite material enhances the transfer of electrons from phthalocyanine to the SnO<sub>2</sub> conduction band, improving light utilization and strengthening the synergistic impact of cobalt phthalocyanine and SnO<sub>2</sub>. Furthermore, the composites demonstrated good stability and recyclability.</p>","PeriodicalId":609,"journal":{"name":"Journal of Applied Spectroscopy","volume":"91 4","pages":"945 - 952"},"PeriodicalIF":0.8000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A New Type of Composite Catalyst α-nBACoPc/SnO2 Synergistic Photo-Catalytic Degradation of Dyes\",\"authors\":\"Yanbing Yin,&nbsp;Bei Jiang,&nbsp;Guopeng Xu,&nbsp;Yang Liu,&nbsp;Zhou Wang,&nbsp;Yongming Feng,&nbsp;Xinyu Sun\",\"doi\":\"10.1007/s10812-024-01804-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The α-nBACoPc/SnO<sub>2</sub> composites were prepared using the in situ synthesis method and characterized by Fourier transform infrared (FT-IR), X-ray powder diff raction (XRD), X-ray photoelectron spectroscopy (XPS), and confirmed by the loading of amino cobalt phthalocyanine on SnO<sub>2</sub>. Conduct photocatalytic degradation experiments used rhodamine B as a simulated pollutant. The composite exhibited a photo-catalytic degradation rate of 83.3%, which was higher than that of α-nBACoPc and SnO<sub>2</sub> alone. The Co–O bond in the composite material enhances the transfer of electrons from phthalocyanine to the SnO<sub>2</sub> conduction band, improving light utilization and strengthening the synergistic impact of cobalt phthalocyanine and SnO<sub>2</sub>. Furthermore, the composites demonstrated good stability and recyclability.</p>\",\"PeriodicalId\":609,\"journal\":{\"name\":\"Journal of Applied Spectroscopy\",\"volume\":\"91 4\",\"pages\":\"945 - 952\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Spectroscopy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10812-024-01804-x\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"SPECTROSCOPY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10812-024-01804-x","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
引用次数: 0

摘要

采用原位合成法制备了α-nBACoPc/SnO2 复合材料,并通过傅立叶变换红外光谱(FT-IR)、X 射线粉末衍射(XRD)和 X 射线光电子能谱(XPS)对其进行了表征。以罗丹明 B 为模拟污染物进行光催化降解实验。复合材料的光催化降解率为 83.3%,高于单独使用 α-nBACoPc 和 SnO2 的光催化降解率。复合材料中的 Co-O 键增强了电子从酞菁向二氧化锡传导带的转移,提高了光的利用率,加强了酞菁钴和二氧化锡的协同作用。此外,复合材料还具有良好的稳定性和可回收性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
A New Type of Composite Catalyst α-nBACoPc/SnO2 Synergistic Photo-Catalytic Degradation of Dyes

The α-nBACoPc/SnO2 composites were prepared using the in situ synthesis method and characterized by Fourier transform infrared (FT-IR), X-ray powder diff raction (XRD), X-ray photoelectron spectroscopy (XPS), and confirmed by the loading of amino cobalt phthalocyanine on SnO2. Conduct photocatalytic degradation experiments used rhodamine B as a simulated pollutant. The composite exhibited a photo-catalytic degradation rate of 83.3%, which was higher than that of α-nBACoPc and SnO2 alone. The Co–O bond in the composite material enhances the transfer of electrons from phthalocyanine to the SnO2 conduction band, improving light utilization and strengthening the synergistic impact of cobalt phthalocyanine and SnO2. Furthermore, the composites demonstrated good stability and recyclability.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
1.30
自引率
14.30%
发文量
145
审稿时长
2.5 months
期刊介绍: Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.
期刊最新文献
Analysis of Spatial Distributions of the Number of Photon Counts in Fluorescence Fluctuation Spectroscopy Identification and Detection of Adulterated Butter by Colorimetry and Near-IR-Spectroscopy Quantitative Spectrophotometric Determination of Cerium Dioxide Nanoparticles in Oxidized Bacterial Cellulose The Anomalous Skin Effect in Metallic Films Spectroscopic and Thermal Study of the Cyanide-Bridged Heteronuclear Compounds [Cd(NH3)(μ-3-Aminomethylpyridine)M(μ-CN)4]N [M: Pd(II) or Pt(II)]
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1