碱激活炉渣在加热-冷却过程中的微观结构变化和相态演变

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-09-12 DOI:10.1007/s12205-024-1379-7
Xiaofeng Han, Jiarun Feng, Penggang Wang, Yanru Wang, Li Tian
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引用次数: 0

摘要

本文研究了碱活性矿渣砂浆在高温下的性能。加热处理后采用了两种冷却方法(即空气冷却和水-弹簧冷却)。研究了加热-冷却过程后 AAS 和 OPC 的力学性能、耐久性、微观结构和相变。与 OPC 试样相比,AAS 试样在经历加热-冷却过程后的抗压强度损失较小,但抗弯强度损失较大。AAS 试样的碳化深度较高,氯离子渗透率较低。AAS-W 试样比 OPC-W 试样具有更高的抗裂纹能力。随着加热温度的升高,AAS 试样的毛细孔比例逐渐增加,在 800°C 时超过了 80%。然而,在 OPC 试样中,800°0;C 时过渡孔隙和毛细管孔隙的含量较高。当温度为 800°C 时,AAS 试样中产生了新物质。
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Microstructure Change and Phases Evolution of Alkali-Activated Slag upon Exposing to the Heating-Cooling Process

This article reports a study on the performance of the alkali activated slag (AAS) mortars upon exposing to the elevated temperatures. Two cooling methods (i.e., cooling in air and water-spring) were adopted following the heating treatment. The mechanical properties, durability, microstructure and phase evolution of AAS and OPC after heating-cooling process were researched. For AAS specimens, the compressive strength loss was smaller, but the flexural strength loss was greater compared to that of OPC specimens after undergoing the heating-cooling process. AAS specimens exhibited higher carbonation depth, and lower penetrated chloride ion. AAS-W specimens shows a higher resistance to cracks formation than OPC-W. With the heating temperature increased, the capillary pore proportion of AAS specimens gradually increased above 80% at 800°0;C. However, high content of transition pores and capillary pores were found at 800°0;C in OPC specimens. The new substances were generated when the temperature was 800°0;C for AAS specimens.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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