从诺特定理看克劳修斯热定理的第一部分

Aaron Beyen, Christian Maes
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引用次数: 0

摘要

亥姆霍兹之后,热力学的力学基础包括第一定律 $d E = \delta Q + \delta W$,以及克劳修斯定理的第一部分 $\delta Q^\text{rev}/T = dS$。由此得出的热孤立系统中准静态变化的熵$S$的不变性与诺特定理(后来才建立)之间的联系。在这一探索中,我们延续了瓦尔德在黑洞热力学中首次提出的想法,以及萨萨(Sasa$\textit{et al.}$)在不同背景下提出的想法。我们同时遵循拉格朗日和哈密尔顿框架,并强调基林方程的作用,以得出热力学一致轨迹的第一定律,最终将 "温度热 "表达为诺特电荷的精确微分。
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First part of Clausius heat theorem in terms of Noether's theorem
After Helmholtz, the mechanical foundation of thermodynamics included the First Law $d E = \delta Q + \delta W$, and the first part of the Clausius heat theorem $\delta Q^\text{rev}/T = dS$. The resulting invariance of the entropy $S$ for quasistatic changes in thermally isolated systems invites a connection with Noether's theorem (only established later). In this quest, we continue an idea, first brought up by Wald in black hole thermodynamics and by Sasa $\textit{et al.}$ in various contexts. We follow both Lagrangian and Hamiltonian frameworks, and emphasize the role of Killing equations for deriving a First Law for thermodynamically consistent trajectories, to end up with an expression of ``heat over temperature'' as an exact differential of a Noether charge.
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