融雪盐对橡胶沥青-钢渣界面粘附力影响的多尺度研究

Le Zhang, Yang Liu, Lan Wang, Zhihua Xue
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引用次数: 0

摘要

为了探索融雪剂对橡胶沥青-钢渣界面粘附力的影响,研究了不同浓度融雪剂下橡胶沥青-钢渣界面的粘附力。研究了不同浓度融雪剂下钢渣橡胶沥青混合料的宏观断裂特性。在微观尺度上测试了不同浓度融雪剂作用下钢渣和橡胶沥青的表面能,并计算了它们的粘附力。该模型用于研究融雪剂作用下的微观表面相互作用。在分子尺度上,构建了橡胶沥青-NaCl 溶液-Ca3SiO5 的界面模型,研究了不同浓度融雪剂作用下钢渣与沥青的相互作用。结果如下:当融雪剂浓度为 8%-12%时,橡胶沥青-钢渣混合料的断裂更倾向于脆性断裂,破坏速度更快;钢渣-橡胶沥青在融雪剂的作用下粘附性减弱,但仍能保持良好的粘附性;在融雪剂浓度达到饱和之前,钢渣-橡胶沥青的粘附性随融雪剂浓度的增加而降低;当融雪剂浓度达到饱和时,NaCl析出并附着在钢渣分子表面,增强了钢渣与橡胶沥青的相互作用;盐浓度的拐点与溶液中析出的溶剂有关。
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Multi-Scale Study on the Effect of Snowmelt Salt on the Interface Adhesion of Rubberized Asphalt–Steel Slag
To explore the effect of snowmelt agent on the adhesion of the rubberized asphalt–steel slag interface, the adhesion of the rubberized asphalt–steel slag interface under different concentrations of snowmelt agent was studied. The macroscopic fracture characteristics of the steel slag-rubberized asphalt mixture under different concentrations of snowmelt salt were studied. The surface energy of steel slag and rubberized asphalt after the action of different concentrations of snowmelt salt was tested at the microscopic scale, and then their adhesion was calculated. It was used to study the microscopic surface interaction under the action of snowmelt agents. At the molecular scale, the interface models of rubberized asphalt–NaCl solution–Ca3SiO5 were constructed, and the interaction between steel slag and asphalt under different concentrations of snowmelt agent was studied. The results show the following: when the concentration of snowmelt agent is 8%–12%, the fracture of the rubberized asphalt–steel slag mixture is more inclined to brittle fracture, and the failure speed is faster; the adhesion of steel slag-rubberized asphalt is weakened under the action of the snowmelt agent, but it can still maintain good adhesion; before the concentration of snowmelt agent reached saturation, the adhesion property of steel slag-rubberized asphalt decreases with the increase of snowmelt agent concentration; when the concentration of snowmelt agent reached saturation, NaCl precipitates and adheres to the molecular surface of steel slag, which enhances the interaction between steel slag and rubberized asphalt; the inflection point with salt concentration is related to the solvent precipitated from the solution.
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