Tingting Yan, Mengting Zhang, Runzhi Yuan, Weili Dai
{"title":"将生物质乙醇和乙酸催化升级为 C4 化学物质","authors":"Tingting Yan, Mengting Zhang, Runzhi Yuan, Weili Dai","doi":"10.1007/s11426-024-2250-9","DOIUrl":null,"url":null,"abstract":"<p>Synthesis of value-added chemicals from biomass is an essential strategy to mitigate the global dependency on fossil resources and achieve the aim of carbon neutrality. Thereinto, ethanol and acetic acid are crucial biomass-derived platform molecules. Recently, catalytic upgrading ethanol and acetic acid into C4 energy-intensive fuels and chemicals via the elongation of carbon backbone has received widespread attention. The primary focus of this review is to systematically describe the recent breakthrough in the conversion of ethanol or acetic acid to C4 chemicals including 1,3-butadiene, <i>n</i>-butenes, isobutene or <i>n</i>-butanol. Special attentions will be given to heterogeneous catalyst design strategies, reaction parameters on the catalytic performance along with the relevant mechanism investigations, as well as their future challenges and opportunities. The present review will provide the detailed insights into the synthesis of C4 chemicals from biomass-derived ethanol and acetic acid and shed a light on the development of highly efficient catalysts.</p>","PeriodicalId":772,"journal":{"name":"Science China Chemistry","volume":null,"pages":null},"PeriodicalIF":10.4000,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Catalytic upgrading biomass-derived ethanol and acetic acid into C4 chemicals\",\"authors\":\"Tingting Yan, Mengting Zhang, Runzhi Yuan, Weili Dai\",\"doi\":\"10.1007/s11426-024-2250-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Synthesis of value-added chemicals from biomass is an essential strategy to mitigate the global dependency on fossil resources and achieve the aim of carbon neutrality. Thereinto, ethanol and acetic acid are crucial biomass-derived platform molecules. Recently, catalytic upgrading ethanol and acetic acid into C4 energy-intensive fuels and chemicals via the elongation of carbon backbone has received widespread attention. The primary focus of this review is to systematically describe the recent breakthrough in the conversion of ethanol or acetic acid to C4 chemicals including 1,3-butadiene, <i>n</i>-butenes, isobutene or <i>n</i>-butanol. Special attentions will be given to heterogeneous catalyst design strategies, reaction parameters on the catalytic performance along with the relevant mechanism investigations, as well as their future challenges and opportunities. The present review will provide the detailed insights into the synthesis of C4 chemicals from biomass-derived ethanol and acetic acid and shed a light on the development of highly efficient catalysts.</p>\",\"PeriodicalId\":772,\"journal\":{\"name\":\"Science China Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":10.4000,\"publicationDate\":\"2024-08-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Science China Chemistry\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://doi.org/10.1007/s11426-024-2250-9\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science China Chemistry","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1007/s11426-024-2250-9","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Catalytic upgrading biomass-derived ethanol and acetic acid into C4 chemicals
Synthesis of value-added chemicals from biomass is an essential strategy to mitigate the global dependency on fossil resources and achieve the aim of carbon neutrality. Thereinto, ethanol and acetic acid are crucial biomass-derived platform molecules. Recently, catalytic upgrading ethanol and acetic acid into C4 energy-intensive fuels and chemicals via the elongation of carbon backbone has received widespread attention. The primary focus of this review is to systematically describe the recent breakthrough in the conversion of ethanol or acetic acid to C4 chemicals including 1,3-butadiene, n-butenes, isobutene or n-butanol. Special attentions will be given to heterogeneous catalyst design strategies, reaction parameters on the catalytic performance along with the relevant mechanism investigations, as well as their future challenges and opportunities. The present review will provide the detailed insights into the synthesis of C4 chemicals from biomass-derived ethanol and acetic acid and shed a light on the development of highly efficient catalysts.
期刊介绍:
Science China Chemistry, co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China and published by Science China Press, publishes high-quality original research in both basic and applied chemistry. Indexed by Science Citation Index, it is a premier academic journal in the field.
Categories of articles include:
Highlights. Brief summaries and scholarly comments on recent research achievements in any field of chemistry.
Perspectives. Concise reports on thelatest chemistry trends of interest to scientists worldwide, including discussions of research breakthroughs and interpretations of important science and funding policies.
Reviews. In-depth summaries of representative results and achievements of the past 5–10 years in selected topics based on or closely related to the research expertise of the authors, providing a thorough assessment of the significance, current status, and future research directions of the field.