常压下 293.15-313.15 K 温度范围内 L-阿拉伯糖和 D-木糖水溶液中 L-谷氨酸的电导率特性和紫外可见光谱研究

IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Russian Journal of Physical Chemistry A Pub Date : 2024-09-11 DOI:10.1134/S0036024424701425
Rupesh Kumar Pradhan,  Sulochana Singh
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引用次数: 0

摘要

摘要 本文采用电导法研究了非必需氨基酸(L-谷氨酸)和碳水化合物(L-阿拉伯糖/D-木糖)在不同温度下的分子相互作用。许多特性,包括极限摩尔电导(\({{\Lambda }}_{{\text{m}}}^{0}\) )、沃尔登积(\({{\Lambda }}_{{\text{m}}}^{0}{{\eta }_{0}}\)、活化能(\({{E}_{text/{A}}}}))、和热力学参数,是通过电导(\(\hat {k}\))测量得到的。所获得的热力学量是根据系统的物理化学相互作用来解释的。小生物大分子(氨基酸)和糖类在溶质-溶剂相互作用中的行为是通过许多参数的影响来显示的,包括浓度、温度、糖类的轴向和赤道 -OH 基团的位置对这些量的影响。亲水-亲水或离子-亲水相互作用在所研究的体系中占主导地位,紫外-可见光谱研究的吸收值也证明了这一点。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Conductometric Properties and UV–Vis Spectroscopic Study of L-Glutamic Acid in Aqueous Solutions of L-Arabinose and D-Xylose in the Temperature Range of 293.15–313.15 K at Atmospheric Pressure

In this work, the electrical conductance approach is used to investigate the molecular interactions between nonessential amino acid (L-glutamic acid) and carbohydrates (L-arabinose/D-xylose) at various temperatures. Many characteristics, including limiting molar conductance (\({{\Lambda }}_{{\text{m}}}^{0}\)), Walden product (\({{\Lambda }}_{{\text{m}}}^{0}{{\eta }_{0}}\)), activation energy (\({{E}_{{\text{A}}}}\)), and thermodynamic parameters, were obtained for the binary and ternary solutions of L-glutamic acid (Glu) from the electrical conductance (\(\hat {k}\)) measurement. The acquired thermodynamic quantities were interpreted in terms of the systems’ physicochemical interactions. The behavior of small biomolecules (amino acid) and saccharides in solute-solvent interactions is shown by the influence of numerous parameters, including concentration, temperature, and the position of axial and equatorial –OH groups of the saccharides, on these quantities. Hydrophilic-hydrophilic or ion-hydrophilic interactions predominate in the systems that are being studied is supported by the UV–Vis spectroscopy investigations’ absorption values.

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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
376
审稿时长
5.1 months
期刊介绍: Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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