冻结在时间中非啮合物理系统综述

IF 3.5 3区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of the American Ceramic Society Pub Date : 2024-08-21 DOI:10.1111/jace.20092
Aaron M. Bossen, John C. Mauro
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引用次数: 0

摘要

非遍历系统的共同特征是内部时间尺度大大超过外部观测时间尺度。许多系统都存在这种打破遍历性的动力学状态,对热力学有着深远的影响。在这项研究中,我们将对非遍历物理系统进行综述,重点关注不同物质系统中非遍历行为的共同起源。我们首先从理论上讨论了能量景观,并对破碎遍历系统的热力学进行了两种处理。然后,我们讨论了几种表现出非啮合行为的特征材料类别,描述了每种材料的啮合分解过程及其特征。我们讨论了示例系统中不同能量相互作用的无序性和挫折感,这可能是非啮合动力学的起源。最后,我们提出了一些有助于识别非啮合行为的注意事项。本综述旨在通过共同的描述来统一一组不同物理系统的行为,以帮助这些研究领域未来的讨论。
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Frozen in time: A review of non-ergodic physical systems

The common feature of non-ergodic systems is an internal timescale that greatly exceeds the external observational timescale t o b s ${t}_{obs}$ . This kinetic state of broken ergodicity occurs in many systems, with profound thermodynamic implications. In this work, we present a review of non-ergodic physical systems focused on the common origins of non-ergodic behavior across diverse material systems. We begin with a theoretical discussion of energy landscapes and two treatments of thermodynamics in broken ergodic systems. We then discuss several characteristic material classes that exhibit non-ergodic behavior, describing the process of ergodic breakdown and its signatures for each. The disordered nature and frustration of different energetic interactions in the example systems are discussed as the possible origin of non-ergodic dynamics. We conclude with several considerations that can assist in the identification of non-ergodic behavior. This review intends to unify the behavior of a diverse group of physical systems with a common description to aid future discussions between these fields of study.

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来源期刊
Journal of the American Ceramic Society
Journal of the American Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
7.50
自引率
7.70%
发文量
590
审稿时长
2.1 months
期刊介绍: The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials. Papers on fundamental ceramic and glass science are welcome including those in the following areas: Enabling materials for grand challenges[...] Materials design, selection, synthesis and processing methods[...] Characterization of compositions, structures, defects, and properties along with new methods [...] Mechanisms, Theory, Modeling, and Simulation[...] JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.
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