D. Sh. Fakhretdinov, I. Sh. Yakupov, A. I. Iskhakova, E. R. Latypova, R. F. Talipov
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Kinetics of the Interaction of Acrylonitrile with Cyclopentadiene in the Diels–Alder Reaction in the Presence of Synthetic Zeolites
The formal kinetics of the interaction of acrylonitrile (AN) and cyclopentadiene (CPD) by the Diels–Alder reaction in the presence of industrial zeolites has been studied. The dependence of the reaction rate constants of interacting components on the geometric properties of porous materials was revealed. The established dependence had a negative extremum at a zeolite pore diameter of 4 Å. It was shown that, in the presence of zeolites, the rate constant of the reaction under consideration was lower than that in the reaction carried out without porous materials.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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