发光二极管驱动的 MOF 催化有氧 C-H 和 C-C 键氧化作用

IF 5.4 3区材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-08-26 DOI:10.1039/d4cy00892h

Mehdi Sheykhan , Mona Bahmani , Masoumeh Abbasnia

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引用次数: 0

摘要

据报道，通过 MOF 催化，一种新型 LED 驱动的有氧 C-H 氧化无需金属源、添加剂或氧化剂。这种方法还能在室温下很好地实现 C-H 键的有氧氧合以及烯烃和炔烃的 C-C 裂解/氧合。在这些条件下，多芳烃也被成功氧化，这表明该方法具有广泛的可扩展性。

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Efficient LED-driven MOF-catalysis for aerobic C–H and C–C bond oxidation†

A novel LED-driven aerobic C–H oxidation is reported via MOF catalysis, eliminating the need for metal sources, additives, or oxidants. This approach also works well with aerobic oxygenation of C–H bonds and C–C cleavage/oxygenation of both alkenes and alkynes all at room temperature. Polyaromatic hydrocarbons were also successfully oxidized under these conditions indicating a broad, extendable scope.

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来源期刊

ACS Applied Energy Materials Materials Science-Materials Chemistry

CiteScore

10.30

自引率

6.20%

发文量

1368

期刊介绍： ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.