{"title":"使用掺铜无定形氧化锆进行芳基硼酸的有氧均偶联反应：催化剂无定形性对反应效率的影响","authors":"","doi":"10.1039/d4cy00694a","DOIUrl":null,"url":null,"abstract":"<div><div>CuO/am-ZrO<sub>2</sub> promotes the homocoupling of boronic acids under air and mild conditions without requiring external additives owing to the presence of easily reducible [CuO<sub>4</sub>] clusters. This catalyst suppresses the adsorption of MeOH solvent, thereby reducing MeOH-related side reactions and enhancing the selectivity and efficiency of the desired reaction.</div></div>","PeriodicalId":66,"journal":{"name":"Catalysis Science & Technology","volume":null,"pages":null},"PeriodicalIF":4.4000,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Aerobic homocoupling of arylboronic acids using Cu-doped amorphous zirconia: impact of catalyst amorphousness on reaction efficiency†\",\"authors\":\"\",\"doi\":\"10.1039/d4cy00694a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>CuO/am-ZrO<sub>2</sub> promotes the homocoupling of boronic acids under air and mild conditions without requiring external additives owing to the presence of easily reducible [CuO<sub>4</sub>] clusters. This catalyst suppresses the adsorption of MeOH solvent, thereby reducing MeOH-related side reactions and enhancing the selectivity and efficiency of the desired reaction.</div></div>\",\"PeriodicalId\":66,\"journal\":{\"name\":\"Catalysis Science & Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2024-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Science & Technology\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2044475324004726\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Science & Technology","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2044475324004726","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Aerobic homocoupling of arylboronic acids using Cu-doped amorphous zirconia: impact of catalyst amorphousness on reaction efficiency†
CuO/am-ZrO2 promotes the homocoupling of boronic acids under air and mild conditions without requiring external additives owing to the presence of easily reducible [CuO4] clusters. This catalyst suppresses the adsorption of MeOH solvent, thereby reducing MeOH-related side reactions and enhancing the selectivity and efficiency of the desired reaction.
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A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis.
Editor-in-chief: Bert Weckhuysen
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Time to first decision (peer reviewed only): 31 days
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