NaCl 和 KCl 溶解度的建模与实验测量：基于激光监测的方法

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-09-04 DOI:10.1007/s10953-024-01415-2

Vahid Jouyban-Gharamaleki, Elaheh Rahimpour, Abolghasem Jouyban

{"title":"NaCl 和 KCl 溶解度的建模与实验测量：基于激光监测的方法","authors":"Vahid Jouyban-Gharamaleki, Elaheh Rahimpour, Abolghasem Jouyban","doi":"10.1007/s10953-024-01415-2","DOIUrl":null,"url":null,"abstract":"<p>This study presented the experimental data for NaCl and KCl solubility in the 1-propanol, 2-propanol, 1-butanol, acetonitrile, and propylene glycol. The solubility values were measured by a laser-based technique at 293.15–313.15 K and the generate data were correlated to some mathematical models and their accuracy was studied by the mean relative deviations for the back-calculated data. Furthermore, the apparent thermodynamic parameters of NaCl and KCl dissolution were also studied according to the van’t Hoff and Gibbs equations.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Modeling and Experimental Measurement of NaCl and KCl Solubility: A Laser Monitoring-Based Method\",\"authors\":\"Vahid Jouyban-Gharamaleki, Elaheh Rahimpour, Abolghasem Jouyban\",\"doi\":\"10.1007/s10953-024-01415-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study presented the experimental data for NaCl and KCl solubility in the 1-propanol, 2-propanol, 1-butanol, acetonitrile, and propylene glycol. The solubility values were measured by a laser-based technique at 293.15–313.15 K and the generate data were correlated to some mathematical models and their accuracy was studied by the mean relative deviations for the back-calculated data. Furthermore, the apparent thermodynamic parameters of NaCl and KCl dissolution were also studied according to the van’t Hoff and Gibbs equations.</p>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-09-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s10953-024-01415-2\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10953-024-01415-2","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

本研究给出了 NaCl 和 KCl 在 1-丙醇、2-丙醇、1-丁醇、乙腈和丙二醇中溶解度的实验数据。溶解度值是在 293.15-313.15 K 温度下通过激光技术测量的，生成的数据与一些数学模型相关联，并通过反向计算数据的平均相对偏差来研究其准确性。此外，还根据范特霍夫方程和吉布斯方程研究了氯化钠和氯化钾溶解的表观热力学参数。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

摘要图片

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Modeling and Experimental Measurement of NaCl and KCl Solubility: A Laser Monitoring-Based Method

This study presented the experimental data for NaCl and KCl solubility in the 1-propanol, 2-propanol, 1-butanol, acetonitrile, and propylene glycol. The solubility values were measured by a laser-based technique at 293.15–313.15 K and the generate data were correlated to some mathematical models and their accuracy was studied by the mean relative deviations for the back-calculated data. Furthermore, the apparent thermodynamic parameters of NaCl and KCl dissolution were also studied according to the van’t Hoff and Gibbs equations.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.

期刊最新文献

Management of Cholesteatoma: Hearing Rehabilitation. Congenital Cholesteatoma. Evaluation of Cholesteatoma. Management of Cholesteatoma: Extension Beyond Middle Ear/Mastoid. Recidivism and Recurrence.