NaCl 和 KCl 溶解度的建模与实验测量：基于激光监测的方法

IF 1.4 4区化学 Q4 CHEMISTRY, PHYSICAL Journal of Solution Chemistry Pub Date : 2024-09-04 DOI:10.1007/s10953-024-01415-2

Vahid Jouyban-Gharamaleki, Elaheh Rahimpour, Abolghasem Jouyban

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引用次数: 0

摘要

本研究给出了 NaCl 和 KCl 在 1-丙醇、2-丙醇、1-丁醇、乙腈和丙二醇中溶解度的实验数据。溶解度值是在 293.15-313.15 K 温度下通过激光技术测量的，生成的数据与一些数学模型相关联，并通过反向计算数据的平均相对偏差来研究其准确性。此外，还根据范特霍夫方程和吉布斯方程研究了氯化钠和氯化钾溶解的表观热力学参数。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Modeling and Experimental Measurement of NaCl and KCl Solubility: A Laser Monitoring-Based Method

This study presented the experimental data for NaCl and KCl solubility in the 1-propanol, 2-propanol, 1-butanol, acetonitrile, and propylene glycol. The solubility values were measured by a laser-based technique at 293.15–313.15 K and the generate data were correlated to some mathematical models and their accuracy was studied by the mean relative deviations for the back-calculated data. Furthermore, the apparent thermodynamic parameters of NaCl and KCl dissolution were also studied according to the van’t Hoff and Gibbs equations.

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来源期刊

Journal of Solution Chemistry 化学-物理化学

CiteScore

2.30

自引率

0.00%

发文量

审稿时长

3-8 weeks

期刊介绍： Journal of Solution Chemistry offers a forum for research on the physical chemistry of liquid solutions in such fields as physical chemistry, chemical physics, molecular biology, statistical mechanics, biochemistry, and biophysics. The emphasis is on papers in which the solvent plays a dominant rather than incidental role. Featured topics include experimental investigations of the dielectric, spectroscopic, thermodynamic, transport, or relaxation properties of both electrolytes and nonelectrolytes in liquid solutions.