Haoxiang Li, Wei Zheng, Bin Du, Huang Zhang, Huaqiang Yin, Xuedong He, Tao Ma, Xingtuan Yang
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The results show that: the Inconel 617 alloy undergoes similar oxidation behavior and the degree of oxidation is very close in three groups of atmospheres with large differences in oxygen content; the alloy should show two oxidation mechanisms, linear oxidation and parabolic oxidation, during the oxidation process; the parabolic rate constant and of the alloy is a constant value and does not vary with large changes in oxygen concentration, but when the experimental temperature changes, the oxidation rate constants of the alloy change, and the lowering of the temperature leads to the lowering of the oxidation rate constants; When experimental temperature is at 950 °C, the alloy continues to undergo a “microclimatic reaction” in the atmosphere of He-ppmO, and the microclimatic reaction disappears when the experimental temperature is lowered to 750 °C; In He-ppmO environment, gas chromatograph can be used instead of thermogravimetric analyzer for real-time monitoring.","PeriodicalId":19272,"journal":{"name":"Nuclear Engineering and Technology","volume":null,"pages":null},"PeriodicalIF":2.6000,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Corrosion studies of Inconel 617 in high temperature air and He-ppmO2 atmospheres\",\"authors\":\"Haoxiang Li, Wei Zheng, Bin Du, Huang Zhang, Huaqiang Yin, Xuedong He, Tao Ma, Xingtuan Yang\",\"doi\":\"10.1016/j.net.2024.08.023\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Air ingress accident is one of the typical accident conditions in Very High Temperature Reactors (VHTRs). This work investigates the oxidation kinetics, corrosion behavior and mechanism of Inconel 617 alloy in different oxygen concentration atmospheres under air ingress accident. The impact of O concentration and oxidation time of the alloy corrosion is investigated. A gas chromatograph was used to measure the impurity content in real time during the helium experiments. After the experiments, the alloys were characterized by electronic balance, were analyzed by Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), X-ray diffraction (XRD) and carbon and sulfur analyzer. The results show that: the Inconel 617 alloy undergoes similar oxidation behavior and the degree of oxidation is very close in three groups of atmospheres with large differences in oxygen content; the alloy should show two oxidation mechanisms, linear oxidation and parabolic oxidation, during the oxidation process; the parabolic rate constant and of the alloy is a constant value and does not vary with large changes in oxygen concentration, but when the experimental temperature changes, the oxidation rate constants of the alloy change, and the lowering of the temperature leads to the lowering of the oxidation rate constants; When experimental temperature is at 950 °C, the alloy continues to undergo a “microclimatic reaction” in the atmosphere of He-ppmO, and the microclimatic reaction disappears when the experimental temperature is lowered to 750 °C; In He-ppmO environment, gas chromatograph can be used instead of thermogravimetric analyzer for real-time monitoring.\",\"PeriodicalId\":19272,\"journal\":{\"name\":\"Nuclear Engineering and Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-08-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nuclear Engineering and Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1016/j.net.2024.08.023\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"NUCLEAR SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nuclear Engineering and Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1016/j.net.2024.08.023","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"NUCLEAR SCIENCE & TECHNOLOGY","Score":null,"Total":0}
Corrosion studies of Inconel 617 in high temperature air and He-ppmO2 atmospheres
Air ingress accident is one of the typical accident conditions in Very High Temperature Reactors (VHTRs). This work investigates the oxidation kinetics, corrosion behavior and mechanism of Inconel 617 alloy in different oxygen concentration atmospheres under air ingress accident. The impact of O concentration and oxidation time of the alloy corrosion is investigated. A gas chromatograph was used to measure the impurity content in real time during the helium experiments. After the experiments, the alloys were characterized by electronic balance, were analyzed by Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), X-ray diffraction (XRD) and carbon and sulfur analyzer. The results show that: the Inconel 617 alloy undergoes similar oxidation behavior and the degree of oxidation is very close in three groups of atmospheres with large differences in oxygen content; the alloy should show two oxidation mechanisms, linear oxidation and parabolic oxidation, during the oxidation process; the parabolic rate constant and of the alloy is a constant value and does not vary with large changes in oxygen concentration, but when the experimental temperature changes, the oxidation rate constants of the alloy change, and the lowering of the temperature leads to the lowering of the oxidation rate constants; When experimental temperature is at 950 °C, the alloy continues to undergo a “microclimatic reaction” in the atmosphere of He-ppmO, and the microclimatic reaction disappears when the experimental temperature is lowered to 750 °C; In He-ppmO environment, gas chromatograph can be used instead of thermogravimetric analyzer for real-time monitoring.
期刊介绍:
Nuclear Engineering and Technology (NET), an international journal of the Korean Nuclear Society (KNS), publishes peer-reviewed papers on original research, ideas and developments in all areas of the field of nuclear science and technology. NET bimonthly publishes original articles, reviews, and technical notes. The journal is listed in the Science Citation Index Expanded (SCIE) of Thomson Reuters.
NET covers all fields for peaceful utilization of nuclear energy and radiation as follows:
1) Reactor Physics
2) Thermal Hydraulics
3) Nuclear Safety
4) Nuclear I&C
5) Nuclear Physics, Fusion, and Laser Technology
6) Nuclear Fuel Cycle and Radioactive Waste Management
7) Nuclear Fuel and Reactor Materials
8) Radiation Application
9) Radiation Protection
10) Nuclear Structural Analysis and Plant Management & Maintenance
11) Nuclear Policy, Economics, and Human Resource Development