烯丙基醚的电化学三氧化反应

Synthesis Pub Date : 2024-09-03 DOI:10.1055/s-0040-1720135
Yong Jiang, Yajuan Li, Chen Zhu, Tao Shen
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引用次数: 0

摘要

三氧合反应是一种非常有效的方法,可以利用简单易得的原材料,通过加入三个 C-O 键,快速增加分子的复杂性。在本研究中,我们介绍了一种烯丙基醚的电化学三氧合反应方案,它可以在不使用外部化学氧化剂的情况下合成多种三乙酰氧基化产物。这些产品很难通过传统方法获得,凸显了电化学在促进可持续合成方面的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Electrochemical Trioxygenation of Allylarenes

Trioxygenation is a highly effective method for rapidly increasing molecular complexity by incorporating three C–O bonds from simple, readily available raw materials. In this study, we present an electrochemical trioxygenation protocol for allylarenes, which enables the synthesis of a diverse array of triacetoxylation products without external chemical oxidants. These products, which are difficult to obtain through conventional methods, highlight the potential of electrochemistry in promoting sustainable synthesis.

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