硫氰酸咔唑和二/三苯基胺的溶剂控制分歧合成

Synthesis Pub Date : 2024-08-26 DOI:10.1055/a-2378-4540
You-Hui Tang, Peng Chen, Jin Yin, Jianghuan Shi, Yi-Jun Jiang
{"title":"硫氰酸咔唑和二/三苯基胺的溶剂控制分歧合成","authors":"You-Hui Tang, Peng Chen, Jin Yin, Jianghuan Shi, Yi-Jun Jiang","doi":"10.1055/a-2378-4540","DOIUrl":null,"url":null,"abstract":"<p>A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH<sub>3</sub>CN/H<sub>2</sub>O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines was achieved. The salient features of this transformation include simple and mild reaction conditions, easily available substrates, and broad substrate scope.</p> ","PeriodicalId":501298,"journal":{"name":"Synthesis","volume":"31 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Solvent-Controlled Divergent Synthesis of Thiocyanated Carbazoles and Di/Triphenylamines\",\"authors\":\"You-Hui Tang, Peng Chen, Jin Yin, Jianghuan Shi, Yi-Jun Jiang\",\"doi\":\"10.1055/a-2378-4540\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH<sub>3</sub>CN/H<sub>2</sub>O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines was achieved. The salient features of this transformation include simple and mild reaction conditions, easily available substrates, and broad substrate scope.</p> \",\"PeriodicalId\":501298,\"journal\":{\"name\":\"Synthesis\",\"volume\":\"31 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-08-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1055/a-2378-4540\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1055/a-2378-4540","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

开发了一种咔唑和二/三苯基胺的溶剂控制发散硫氰酸化方法。使用 CH3CN/H2O (3:1) 或 DMSO 作为溶剂,实现了咔唑和二/三苯基胺的单硫氰酸化和二硫氰酸化的溶剂控制发散合成的简便高效的方案。这种转化的显著特点包括反应条件简单温和、底物容易获得以及底物范围广泛。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Solvent-Controlled Divergent Synthesis of Thiocyanated Carbazoles and Di/Triphenylamines

A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH3CN/H2O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines was achieved. The salient features of this transformation include simple and mild reaction conditions, easily available substrates, and broad substrate scope.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Facile Synthesis of Silanols via Cesium Carbonate Catalyzed Hydrosilanes with Water Discovery Process Chemistry: An Innovation Hub at the Interface of Academia, the Pharmaceutical Industry, and Contract Research Organization Accessing a Medicinal-Chemistry-Relevant Chemical Space with sp2–sp3 Hybrid Heterocyclic Fragments Recent Advances in Diazophosphonate Chemistry: Reactions and Transformations Recent Advances in Fluoroalkylation Strategies: Exploring Novel Reactivities and Synthetic Applications of Sulfone- and Sulfinate-Based Reagents for Mono-, Di-, and Trifluoromethylations
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1