You-Hui Tang, Peng Chen, Jin Yin, Jianghuan Shi, Yi-Jun Jiang
{"title":"硫氰酸咔唑和二/三苯基胺的溶剂控制分歧合成","authors":"You-Hui Tang, Peng Chen, Jin Yin, Jianghuan Shi, Yi-Jun Jiang","doi":"10.1055/a-2378-4540","DOIUrl":null,"url":null,"abstract":"<p>A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH<sub>3</sub>CN/H<sub>2</sub>O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines was achieved. The salient features of this transformation include simple and mild reaction conditions, easily available substrates, and broad substrate scope.</p> ","PeriodicalId":501298,"journal":{"name":"Synthesis","volume":"31 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Solvent-Controlled Divergent Synthesis of Thiocyanated Carbazoles and Di/Triphenylamines\",\"authors\":\"You-Hui Tang, Peng Chen, Jin Yin, Jianghuan Shi, Yi-Jun Jiang\",\"doi\":\"10.1055/a-2378-4540\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH<sub>3</sub>CN/H<sub>2</sub>O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines was achieved. The salient features of this transformation include simple and mild reaction conditions, easily available substrates, and broad substrate scope.</p> \",\"PeriodicalId\":501298,\"journal\":{\"name\":\"Synthesis\",\"volume\":\"31 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-08-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1055/a-2378-4540\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1055/a-2378-4540","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Solvent-Controlled Divergent Synthesis of Thiocyanated Carbazoles and Di/Triphenylamines
A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH3CN/H2O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines was achieved. The salient features of this transformation include simple and mild reaction conditions, easily available substrates, and broad substrate scope.