加压 Re$_{0.10}$Mo$_{0.90}$B$_2$ 中的超导现象

S. Sinha, J. Lim, Z. Li, J. S. Kim, A. C. Hire, P. M. Dee, R. S. Kumar, D. Popov, R. J. Hemley, R. G. Hennig, P. J. Hirschfeld, G. R. Stewart, J. J. Hamlin
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引用次数: 0

摘要

最近在 70 GPa 以上的 MoB$_2$ 中令人惊讶地发现了临界温度 $T_c$ = 32 K 的超导电性,这促使人们寻找可能在类似的高 $T_c$ 值和较低压力下超导的相关材料。我们研究了 Re$_{0.10}$Mo$_{0.90}$B$_2$ 在 170 GPa 下的超导和结构特性。从 48 GPa 开始出现从 Re3m 到 P6/mmm 的结构相变,超导现象在 44 GPa 以上首次出现。临界温度随压力的增加而升高。只有在 150 GPa 以上才能观察到完全的电阻转变,在这里也达到了 30 K 的最高起始 T_c$。释放压力后,发现高压超导相是稳定的。在卸载过程中,可以观察到完全的电阻超导转变,一直下降到 20 GPa(起始温度为 20 K)。我们的研究结果表明,P6/mmm 结构是观测到的超导现象的原因。
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Superconductivity in pressurized Re$_{0.10}$Mo$_{0.90}$B$_2$
The recent surprising discovery of superconductivity with critical temperature $T_c$ = 32 K in MoB$_2$ above 70 GPa has led to the search for related materials that may superconduct at similarly high $T_c$ values and lower pressures. We have studied the superconducting and structural properties of Re$_{0.10}$Mo$_{0.90}$B$_2$ to 170 GPa. A structural phase transition from R3m to P6/mmm commences at 48 GPa, with the first signatures of superconductivity appearing above 44 GPa. The critical temperature is observed to increase with pressure. A complete resistive transition is observed only above 150 GPa, where the highest onset $T_c$ of 30 K is also achieved. Upon releasing pressure, the high pressure superconducting phase is found to be metastable. During unloading, a complete resistive superconducting transition is observed all the way down to 20 GPa (with onset $T_c \sim 20$ K). Our results suggest that the P6/mmm structure is responsible for the observed superconductivity.
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