过冷液体的非加性随机模型:玻璃科学的新视角

IF 1.6 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER The European Physical Journal B Pub Date : 2024-08-12 DOI:10.1140/epjb/s10051-024-00761-w
Antonio Cesar do Prado Rosa Jr., Elias Brito, Wanisson Santana, Clebson Cruz
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摘要

摘要 我们对用于过冷液体的非加性随机模型(NSM)进行了综述,这是一种用于扩散过程的有效方法,为这些材料中的非阿伦尼乌斯动力学提供了合适的解释。NSM 以一类非均质连续性方程为基础,提供了用于模拟脆性液体中粘度和扩散性热行为的函数。该模型定义了区分超阿伦尼斯和亚阿伦尼斯过程的严格物理标准,建立了稳健的脆性标度,描述了安格尔图中从脆到强的曲线,并为实验粘度数据提供了精确的拟合方程,与其他粘度经典模型一样有效。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Non-additive stochastic model for supercooled liquids: new perspectives for glass science

We present a review of the Non-additive Stochastic Model (NSM) for supercooled liquids, an efficient approach for diffusive processes that provide a suitable interpretation for the non-Arrhenius dynamics in these materials. Based on a class of non-homogeneous continuity equations, the NSM provides functions to model the thermal behavior of the viscosity and diffusivity in fragile liquids. The model defines a rigorous physical criterion that distinguishes super-Arrhenius from sub-Arrhenius processes, establishes a robust scale of fragility, describes fragile-to-strong curves in Angell’s plot, and provides an accurate fitting equation for experimental viscosity data as effective as others viscosity classic models.

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来源期刊
The European Physical Journal B
The European Physical Journal B 物理-物理:凝聚态物理
CiteScore
2.80
自引率
6.20%
发文量
184
审稿时长
5.1 months
期刊介绍: Solid State and Materials; Mesoscopic and Nanoscale Systems; Computational Methods; Statistical and Nonlinear Physics
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