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引用次数: 0
摘要
本文提出了结合迈克尔-门顿(MM)消耗和不可逆同二聚化过程的同步底物消除问题的解析解。隐式解涉及对数和反切函数,与微分方程的数值解完全一致。此外,还提出了广义动力学问题的解决方案,该问题同时结合了 MM 动力学与一阶和二阶过程。还给出了这些问题的半衰期和曲线下面积的精确表达式。
Analytical solution to the simultaneous Michaelis-Menten and second-order kinetics problem
An analytic solution is presented for the simultaneous substrate elimination problem that combines Michaelis-Menten (MM) consumption with an irreversible homo-dimerization process. The implicit solution involves logarithm and inverse tangent functions and perfectly agrees with the numerical solution of the differential equation. A solution is also presented for the generalized dynamical problem that simultaneously combines MM kinetics with first and second-order processes. The exact expressions for the half-life and the area under the curve are also presented for these problems.
期刊介绍:
Reaction Kinetics, Mechanisms and Catalysis is a medium for original contributions in the following fields:
-kinetics of homogeneous reactions in gas, liquid and solid phase;
-Homogeneous catalysis;
-Heterogeneous catalysis;
-Adsorption in heterogeneous catalysis;
-Transport processes related to reaction kinetics and catalysis;
-Preparation and study of catalysts;
-Reactors and apparatus.
Reaction Kinetics, Mechanisms and Catalysis was formerly published under the title Reaction Kinetics and Catalysis Letters.