镍催化的偶氮烯在水中高效化学选择性还原为偶氮肼

IF 2.7 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY New Journal of Chemistry Pub Date : 2024-09-09 DOI:10.1039/D4NJ03477E

Dawei Gong, Qixuan Li, Yufei Li, Qinghua Yang, Caiyu Gao, Jiku Wang and Lina Zhao

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摘要

我们开发了一种在水中利用 NH3BH3 以镍催化合成肼的方法。在镍催化剂的促进下，这种简单的合成方法表现出极佳的化学选择性，提供了 22 个无需柱层析的例子。该策略引入了一种新型的镍催化水中还原系统，有望在工业领域得到应用。

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Nickel-catalyzed highly efficient chemoselective reduction of azoarenes to hydrazoarenes in water†

A nickel-catalyzed synthesis of hydrazoarenes utilizing NH₃BH₃ in water has been developed. This simple synthesis, facilitated by a nickel catalyst, exhibits excellent chemoselectivity, with 22 examples provided without the need for any column chromatography. This strategy introduces a novel nickel-catalyzed reduction system in water, holding promise for industrial applications.

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