温度对聚氯乙烯泡沫机械性能的影响

IF 3.2 4区 工程技术 Q2 CHEMISTRY, APPLIED Journal of Cellular Plastics Pub Date : 2024-09-09 DOI:10.1177/0021955x241281878
Michelle S Hoo Fatt, Anudeep R Vedire, Akshay K Pakala
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引用次数: 0

摘要

通过实验确定了 Divinycell 聚氯乙烯泡沫在 -60 至 +80°C 宽范围环境温度下的机械行为特征。实验发现,泡沫的横向各向同性特性(包括模量、强度和延展性)随韧性到脆性转变温度(-60 至 -50°C)和玻璃化转变温度(95 至 100°C)之间的温度变化而变化。弹性模量和屈服强度随着温度从 -60°C 上升到 +80°C 呈线性下降。在整个温度范围内,抗压强度也随着温度的升高而稳步下降。相比之下,拉伸强度和剪切强度仅在温度升至 23°C(室温)以上时才出现显著下降。温度低于 23°C 时,拉伸强度和剪切强度变化不大。当温度从 +80°C 降至 -40°C 时,拉伸和剪切延展性急剧下降,并在 -60 至 -40°C 之间趋于稳定,这接近韧性到脆性的过渡区域。拉伸和剪切断裂表面的碎裂图证实,脆性断裂发生在-60°C,而韧性撕裂发生在+60°C。通过推导方程,可以用室温值预测任何温度下的模量、屈服强度、压缩强度、拉伸强度和剪切强度以及延展性。
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Effect of temperature on the mechanical behavior of pvc foams
Experiments were conducted to characterize the mechanical behavior of Divinycell PVC foams over a wide range of environmental temperatures, from −60 to +80°C. Transversely isotropic properties of the foams, including modulus, strength, and ductility, were found to vary with temperatures between the ductile-to-brittle transition temperature (−60 to −50°C) and just under the glass transition temperature (95 to 100°C). The elastic modulus and yield strength decreased linearly as the temperature increased from −60 to +80°C. Compressive strength also decreased steadily with increasing temperature over the entire temperature range. In contrast, tensile and shear strengths only showed a significant decrease in values as the temperature rose above 23°C (room temperature). Below 23°C, there was a minor change in tensile and shear strengths. Tensile and shear ductility decreased sharply as the temperature decreased from +80°C to −40°C and stabilized between −60 and −40°C, which is close to the ductile-to-brittle transition region. Fractography of the tensile and shear fracture surfaces confirmed brittle fracture at −60°C and ductile tearing at +60°C. Equations were derived to predict modulus, yield strength, compressive, tensile and shear strengths, and ductility at any temperature in terms of room temperature values.
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来源期刊
Journal of Cellular Plastics
Journal of Cellular Plastics 工程技术-高分子科学
CiteScore
5.00
自引率
16.00%
发文量
19
审稿时长
3 months
期刊介绍: The Journal of Cellular Plastics is a fully peer reviewed international journal that publishes original research and review articles covering the latest advances in foamed plastics technology.
期刊最新文献
I-WP geometry structural assessment: A theoretical, experimental, and numerical analysis Foam density measurement using a 3D scanner Effect of temperature on the mechanical behavior of pvc foams Preparation and energy absorption of flexible polyurethane foam with hollow glass microsphere A review on the mechanical behaviour of microcellular and nanocellular polymeric foams: What is the effect of the cell size reduction?
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